Abstract
The near-infrared emission spectrum of CoS has been recorded at a resolution of 0.04 cm(-1) using a Fourier transform spectrometer. Gas-phase CoS was produced by the reaction of cobalt vapor and CS, vapor at about 3000 K in a carbon tube furnace. Two electronic transitions were observed for the first time in the 3200-6000 cm(-1) region and have been assigned to the A(4)Phi(i)-X-4 Delta(i) and B-4 Pi(i)-X-4 Delta(i) transitions. The 0-0 bands for all four sub-bands of the A(4)Phi(i)-X-4 Delta(i) transition, and the 0-0, 0-1, 1-0, and 1-1 bands for the 5/2-7/2 sub-band of the B-4 Pi(i)-X-4 Delta(i) transition were rotationally analyzed. Combined with the previous microwave data from the literature, the present data were fitted using the usual Hund's case (c) energy level expressions, and spectroscopic constants were obtained for the X-4 Delta(i), A(4)Phi(i), and B-4 Pi(i) states of CoS. A Hund's case (a) fit was also carried out for the A(4)Phi(i)-X-4 Delta(i) transition. The presence of a low-lying (4)Phi(i) state for both CoS and Coo was not anticipated based on previous experimental and theoretical work. (C) 2006 Elsevier Inc. All rights reserved.
| Original language | English |
|---|---|
| Pages (from-to) | 255-259 |
| Number of pages | 5 |
| Journal | JOURNAL OF MOLECULAR SPECTROSCOPY |
| Volume | 236 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Apr 2006 |
Keywords
- transition metal sulfides
- near-infrared electronic spectra
- Fourier transform emission spectroscopy
- ELECTRONIC-STRUCTURE
- GROUND-STATE
- GASEOUS COO
- SPECTRUM
- OXIDES
- SYSTEM
- PARAMETERS
- MONOXIDES
- HYPERFINE
- MOLECULES