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Inherently Chiral Upper-Rim-Bridged Calix[4]arenes Possessing a Seven Membered Ring

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Inherently Chiral Upper-Rim-Bridged Calix[4]arenes Possessing a Seven Membered Ring. / Tlustý, Martin; Slavík, Petr; Kohout, Michal; Eigner, Václav; Lhoták, Pavel.

In: Organic Letters, Vol. 19, No. 11, 02.06.2017, p. 2933-2936.

Research output: Contribution to journalArticle

Harvard

Tlustý, M, Slavík, P, Kohout, M, Eigner, V & Lhoták, P 2017, 'Inherently Chiral Upper-Rim-Bridged Calix[4]arenes Possessing a Seven Membered Ring', Organic Letters, vol. 19, no. 11, pp. 2933-2936. https://doi.org/10.1021/acs.orglett.7b01170

APA

Tlustý, M., Slavík, P., Kohout, M., Eigner, V., & Lhoták, P. (2017). Inherently Chiral Upper-Rim-Bridged Calix[4]arenes Possessing a Seven Membered Ring. Organic Letters, 19(11), 2933-2936. https://doi.org/10.1021/acs.orglett.7b01170

Vancouver

Tlustý M, Slavík P, Kohout M, Eigner V, Lhoták P. Inherently Chiral Upper-Rim-Bridged Calix[4]arenes Possessing a Seven Membered Ring. Organic Letters. 2017 Jun 2;19(11):2933-2936. https://doi.org/10.1021/acs.orglett.7b01170

Author

Tlustý, Martin ; Slavík, Petr ; Kohout, Michal ; Eigner, Václav ; Lhoták, Pavel. / Inherently Chiral Upper-Rim-Bridged Calix[4]arenes Possessing a Seven Membered Ring. In: Organic Letters. 2017 ; Vol. 19, No. 11. pp. 2933-2936.

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@article{2210281964614c94aa5562cb70bab26d,
title = "Inherently Chiral Upper-Rim-Bridged Calix[4]arenes Possessing a Seven Membered Ring",
abstract = "The mercuration of calix[4]arene immobilized in the cone conformation allowed the introduction of an amino group at the meta position of the basic skeleton. Acylation and subsequent intramolecular Bischler-Napieralski-type cyclization led to a novel type of bridged calixarene containing a seven-membered ring. These compounds with an enlarged and rigidified cavity represent a unique and inherently chiral system that may potentially be applicable for the design of chiral receptors. The absolute configuration of one enantiomer, obtained by resolution of the racemate using chiral HPLC, was assigned by single-crystal structure determination.",
keywords = "Journal Article, Research Support, Non-U.S. Gov't",
author = "Martin Tlust{\'y} and Petr Slav{\'i}k and Michal Kohout and V{\'a}clav Eigner and Pavel Lhot{\'a}k",
year = "2017",
month = "6",
day = "2",
doi = "10.1021/acs.orglett.7b01170",
language = "English",
volume = "19",
pages = "2933--2936",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "11",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Inherently Chiral Upper-Rim-Bridged Calix[4]arenes Possessing a Seven Membered Ring

AU - Tlustý, Martin

AU - Slavík, Petr

AU - Kohout, Michal

AU - Eigner, Václav

AU - Lhoták, Pavel

PY - 2017/6/2

Y1 - 2017/6/2

N2 - The mercuration of calix[4]arene immobilized in the cone conformation allowed the introduction of an amino group at the meta position of the basic skeleton. Acylation and subsequent intramolecular Bischler-Napieralski-type cyclization led to a novel type of bridged calixarene containing a seven-membered ring. These compounds with an enlarged and rigidified cavity represent a unique and inherently chiral system that may potentially be applicable for the design of chiral receptors. The absolute configuration of one enantiomer, obtained by resolution of the racemate using chiral HPLC, was assigned by single-crystal structure determination.

AB - The mercuration of calix[4]arene immobilized in the cone conformation allowed the introduction of an amino group at the meta position of the basic skeleton. Acylation and subsequent intramolecular Bischler-Napieralski-type cyclization led to a novel type of bridged calixarene containing a seven-membered ring. These compounds with an enlarged and rigidified cavity represent a unique and inherently chiral system that may potentially be applicable for the design of chiral receptors. The absolute configuration of one enantiomer, obtained by resolution of the racemate using chiral HPLC, was assigned by single-crystal structure determination.

KW - Journal Article

KW - Research Support, Non-U.S. Gov't

U2 - 10.1021/acs.orglett.7b01170

DO - 10.1021/acs.orglett.7b01170

M3 - Article

VL - 19

SP - 2933

EP - 2936

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 11

ER -