Introducing the reversible chemistry of CO2with diols mediated by organic superbases into polycarbonate synthesis

Yang Chai; Qin Chen; Caijuan Huang; Qiang Zheng; Michael North; Haibo Xie

doi:10.1039/d0gc01197e

Introducing the reversible chemistry of CO₂with diols mediated by organic superbases into polycarbonate synthesis

Yang Chai, Qin Chen, Caijuan Huang, Qiang Zheng, Michael North, Haibo Xie

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The reversible reaction of CO2 with alcohols in the presence of organic bases was successfully developed to be a toolbox for capturing CO2 into polymerizable α,ω-diene functionalized carbonate monomers with high structural diversity. These are applicable for thiol-ene click and ADMET polymerization to produce new libraries of poly(thioether carbonates) and unsaturated aromatic-aliphatic polycarbonates with high molecular weights and satisfactory thermal properties.

Original language	English
Pages (from-to)	4871-4877
Number of pages	7
Journal	Green Chemistry
Volume	22
Issue number	15
DOIs	https://doi.org/10.1039/d0gc01197e
Publication status	Published - 7 Aug 2020

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abstract = "The reversible reaction of CO2 with alcohols in the presence of organic bases was successfully developed to be a toolbox for capturing CO2 into polymerizable α,ω-diene functionalized carbonate monomers with high structural diversity. These are applicable for thiol-ene click and ADMET polymerization to produce new libraries of poly(thioether carbonates) and unsaturated aromatic-aliphatic polycarbonates with high molecular weights and satisfactory thermal properties.",

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AU - North, Michael

AU - Xie, Haibo

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Introducing the reversible chemistry of CO2with diols mediated by organic superbases into polycarbonate synthesis

Abstract

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Introducing the reversible chemistry of CO₂with diols mediated by organic superbases into polycarbonate synthesis