Isolation and structural characterisation of rhodium(iii) ?2-fluoroarene complexes: Experimental verification of predicted regioselectivity

Matthew R. Gyton; Amy E. Kynman; Baptiste Leforestier; Angelo Gallo; Józef R. Lewandowski; Adrian B. Chaplin

doi:10.1039/d0dt01137a

Isolation and structural characterisation of rhodium(iii) ?²-fluoroarene complexes: Experimental verification of predicted regioselectivity

Matthew R. Gyton, Amy E. Kynman, Baptiste Leforestier, Angelo Gallo, Józef R. Lewandowski, Adrian B. Chaplin^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The isolation and solid-state characterisation of complexes featuring partially coordinated benzene, fluorobenzene and all three isomers of difluorobenzene are described. Supported by a DFT analysis, this well-defined homologous series demonstrates the preference for ?²-coordination of fluoroarenesviathe HC?CH sites adjacent to a fluorine substituent.

Original language	English
Pages (from-to)	5791-5793
Number of pages	3
Journal	Dalton Transactions
Volume	49
Issue number	18
DOIs	https://doi.org/10.1039/d0dt01137a
Publication status	Published - 14 May 2020

Bibliographical note

Funding Information:
This work was supported by European Research Council (ERC, grant agreements 637313 and 639907) and Royal Society (UF100592, UF150675). Computing facilities were provided by the Scientific Computing Research Technology Platform of the University of Warwick.

Publisher Copyright:
© The Royal Society of Chemistry 2020.

Access to Document

10.1039/d0dt01137a

Cite this

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title = "Isolation and structural characterisation of rhodium(iii) ?2-fluoroarene complexes: Experimental verification of predicted regioselectivity",

abstract = "The isolation and solid-state characterisation of complexes featuring partially coordinated benzene, fluorobenzene and all three isomers of difluorobenzene are described. Supported by a DFT analysis, this well-defined homologous series demonstrates the preference for ?2-coordination of fluoroarenesviathe HC?CH sites adjacent to a fluorine substituent.",

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doi = "10.1039/d0dt01137a",

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T2 - Experimental verification of predicted regioselectivity

AU - Gyton, Matthew R.

AU - Kynman, Amy E.

AU - Leforestier, Baptiste

AU - Gallo, Angelo

AU - Lewandowski, Józef R.

AU - Chaplin, Adrian B.

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AB - The isolation and solid-state characterisation of complexes featuring partially coordinated benzene, fluorobenzene and all three isomers of difluorobenzene are described. Supported by a DFT analysis, this well-defined homologous series demonstrates the preference for ?2-coordination of fluoroarenesviathe HC?CH sites adjacent to a fluorine substituent.

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