Kinetics of stabilised Criegee intermediates derived from alkene ozonolysis: Reactions with SO₂, H₂O and decomposition under boundary layer conditions

TY - JOUR

T1 - Kinetics of stabilised Criegee intermediates derived from alkene ozonolysis

T2 - Reactions with SO2, H2O and decomposition under boundary layer conditions

AU - Newland, Mike J.

AU - Rickard, Andrew R.

AU - Alam, Mohammed S.

AU - Vereecken, Luc

AU - Muñoz, Amalia

AU - Ródenas, Milagros

AU - Bloss, William J.

PY - 2015/2/15

Y1 - 2015/2/15

N2 - The removal of SO2 in the presence of alkene-ozone systems has been studied for ethene, cis-but-2-ene, trans-but-2-ene and 2,3-dimethyl-but-2-ene, as a function of humidity, under atmospheric boundary layer conditions. The SO2 removal displays a clear dependence on relative humidity for all four alkene-ozone systems confirming a significant reaction for stabilised Criegee intermediates (SCI) with H2O. The observed SO2 removal kinetics are consistent with relative rate constants, k(SCI + H2O)/k(SCI + SO2), of 3.3 (±1.1) × 10-5 for CH2OO, 26 (±10) × 10-5 for CH3CHOO derived from cis-but-2-ene, 33 (±10) × 10-5 for CH3CHOO derived from trans-but-2-ene, and 8.7 (±2.5) × 10-5 for (CH3)2COO derived from 2,3-dimethyl-but-2-ene. The relative rate constants for k(SCI decomposition)/k(SCI + SO2) are -2.3 (±3.5) × 1011 cm-3 for CH2OO, 13 (±43) × 1011 cm-3 for CH3CHOO derived from cis-but-2-ene, -14 (±31) × 1011 cm-3 for CH3CHOO derived from trans-but-2-ene and 63 (±14) × 1011 cm-3 for (CH3)2COO. Uncertainties are ±2σ and represent combined systematic and precision components. These values are derived following the approximation that a single SCI is present for each system; a more comprehensive interpretation, explicitly considering the differing reactivity for syn- and anti-SCI conformers, is also presented. This yields values of 3.5 (±3.1) × 10-4 for k(SCI + H2O)/k(SCI + SO2) of anti-CH3CHOO and 1.2 (±1.1) × 1013 for k(SCI decomposition)/k(SCI + SO2) of syn-CH3CHOO. The reaction of the water dimer with CH2OO is also considered, with a derived value for k(CH2OO + (H2O)2)/k(CH2OO + SO2) of 1.4 (±1.8) × 10-2. The observed SO2 removal rate constants, which technically represent upper limits, are consistent with decomposition being a significant, structure dependent, sink in the atmosphere for syn-SCI.

AB - The removal of SO2 in the presence of alkene-ozone systems has been studied for ethene, cis-but-2-ene, trans-but-2-ene and 2,3-dimethyl-but-2-ene, as a function of humidity, under atmospheric boundary layer conditions. The SO2 removal displays a clear dependence on relative humidity for all four alkene-ozone systems confirming a significant reaction for stabilised Criegee intermediates (SCI) with H2O. The observed SO2 removal kinetics are consistent with relative rate constants, k(SCI + H2O)/k(SCI + SO2), of 3.3 (±1.1) × 10-5 for CH2OO, 26 (±10) × 10-5 for CH3CHOO derived from cis-but-2-ene, 33 (±10) × 10-5 for CH3CHOO derived from trans-but-2-ene, and 8.7 (±2.5) × 10-5 for (CH3)2COO derived from 2,3-dimethyl-but-2-ene. The relative rate constants for k(SCI decomposition)/k(SCI + SO2) are -2.3 (±3.5) × 1011 cm-3 for CH2OO, 13 (±43) × 1011 cm-3 for CH3CHOO derived from cis-but-2-ene, -14 (±31) × 1011 cm-3 for CH3CHOO derived from trans-but-2-ene and 63 (±14) × 1011 cm-3 for (CH3)2COO. Uncertainties are ±2σ and represent combined systematic and precision components. These values are derived following the approximation that a single SCI is present for each system; a more comprehensive interpretation, explicitly considering the differing reactivity for syn- and anti-SCI conformers, is also presented. This yields values of 3.5 (±3.1) × 10-4 for k(SCI + H2O)/k(SCI + SO2) of anti-CH3CHOO and 1.2 (±1.1) × 1013 for k(SCI decomposition)/k(SCI + SO2) of syn-CH3CHOO. The reaction of the water dimer with CH2OO is also considered, with a derived value for k(CH2OO + (H2O)2)/k(CH2OO + SO2) of 1.4 (±1.8) × 10-2. The observed SO2 removal rate constants, which technically represent upper limits, are consistent with decomposition being a significant, structure dependent, sink in the atmosphere for syn-SCI.

UR - http://www.scopus.com/inward/record.url?scp=84944180421&partnerID=8YFLogxK

U2 - 10.1039/c4cp04186k

DO - 10.1039/c4cp04186k

M3 - Article

AN - SCOPUS:84944180421

SN - 1463-9076

VL - 17

SP - 4076

EP - 4088

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 6

ER -