Layered compounds incorporating 9,9 '-spirobifluorene: Hydrogen-bonded and metal-organic networks derived from 9,9 '-spirobifluorene-2,2 ',7,7 '-tetracarboxylic acid

Peter K. Clews; Richard E. Douthwaite; Benson M. Kariuki; Terry Moore; Miguel Taboada

doi:10.1021/cg060007d

Layered compounds incorporating 9,9 '-spirobifluorene: Hydrogen-bonded and metal-organic networks derived from 9,9 '-spirobifluorene-2,2 ',7,7 '-tetracarboxylic acid

Peter K. Clews, Richard E. Douthwaite, Benson M. Kariuki, Terry Moore, Miguel Taboada

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A new tetracarboxylic acid derivative of 9,9'-spirobifluorene (9,9'-spirobifluorene-2,2',7,7'-tetracarboxylic acid (SBFTCA) ( 3)) has been prepared and crystallized as a THF solvate (3 center dot THF). Hydrogen bonding between adjacent molecules of 3 results in a ( 4,4) layer topology and non-interpenetrating AB layer stacking. The topology of 3 gives rise to pores that are occupied by disordered THF molecules. Under hydrothermal conditions, a mixture of 3, methylimidazole, and Co(NO3)(2) gives single crystals of a layered network ( 4) comprising the tetracarboxylate of 3 linked by Co(II) ions. The structure of 4 is similar to that of 3, THF exhibiting an AB motif, with two methylimidazole ligands per cobalt atom occupying the remaining volume.

Original language	English
Pages (from-to)	1991-1994
Number of pages	4
Journal	CRYSTAL GROWTH DESIGN
Volume	6
Issue number	9
DOIs	https://doi.org/10.1021/cg060007d
Publication status	Published - 6 Sept 2006

Keywords

COORDINATION POLYMERS
ENANTIOSELECTIVE COMPLEXATION
MOLECULAR TECTONICS
DICARBOXYLIC-ACIDS
RATIONAL DESIGN
BUILDING UNITS
FRAMEWORKS
DERIVATIVES
RECOGNITION
COBALT(II)

Access to Document

10.1021/cg060007d

Cite this

@article{13a1b8a450b84fa489cd0a79e47467b9,

title = "Layered compounds incorporating 9,9 '-spirobifluorene: Hydrogen-bonded and metal-organic networks derived from 9,9 '-spirobifluorene-2,2 ',7,7 '-tetracarboxylic acid",

abstract = "A new tetracarboxylic acid derivative of 9,9'-spirobifluorene (9,9'-spirobifluorene-2,2',7,7'-tetracarboxylic acid (SBFTCA) ( 3)) has been prepared and crystallized as a THF solvate (3 center dot THF). Hydrogen bonding between adjacent molecules of 3 results in a ( 4,4) layer topology and non-interpenetrating AB layer stacking. The topology of 3 gives rise to pores that are occupied by disordered THF molecules. Under hydrothermal conditions, a mixture of 3, methylimidazole, and Co(NO3)(2) gives single crystals of a layered network ( 4) comprising the tetracarboxylate of 3 linked by Co(II) ions. The structure of 4 is similar to that of 3, THF exhibiting an AB motif, with two methylimidazole ligands per cobalt atom occupying the remaining volume.",

keywords = "COORDINATION POLYMERS, ENANTIOSELECTIVE COMPLEXATION, MOLECULAR TECTONICS, DICARBOXYLIC-ACIDS, RATIONAL DESIGN, BUILDING UNITS, FRAMEWORKS, DERIVATIVES, RECOGNITION, COBALT(II)",

author = "Clews, {Peter K.} and Douthwaite, {Richard E.} and Kariuki, {Benson M.} and Terry Moore and Miguel Taboada",

year = "2006",

month = sep,

day = "6",

doi = "10.1021/cg060007d",

language = "English",

volume = "6",

pages = "1991--1994",

journal = "CRYSTAL GROWTH DESIGN",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "9",

}

Layered compounds incorporating 9,9 '-spirobifluorene: Hydrogen-bonded and metal-organic networks derived from 9,9 '-spirobifluorene-2,2 ',7,7 '-tetracarboxylic acid. / Clews, Peter K.; Douthwaite, Richard E.; Kariuki, Benson M. et al.
In: CRYSTAL GROWTH DESIGN, Vol. 6, No. 9, 06.09.2006, p. 1991-1994.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Layered compounds incorporating 9,9 '-spirobifluorene: Hydrogen-bonded and metal-organic networks derived from 9,9 '-spirobifluorene-2,2 ',7,7 '-tetracarboxylic acid

AU - Clews, Peter K.

AU - Douthwaite, Richard E.

AU - Kariuki, Benson M.

AU - Moore, Terry

AU - Taboada, Miguel

PY - 2006/9/6

Y1 - 2006/9/6

N2 - A new tetracarboxylic acid derivative of 9,9'-spirobifluorene (9,9'-spirobifluorene-2,2',7,7'-tetracarboxylic acid (SBFTCA) ( 3)) has been prepared and crystallized as a THF solvate (3 center dot THF). Hydrogen bonding between adjacent molecules of 3 results in a ( 4,4) layer topology and non-interpenetrating AB layer stacking. The topology of 3 gives rise to pores that are occupied by disordered THF molecules. Under hydrothermal conditions, a mixture of 3, methylimidazole, and Co(NO3)(2) gives single crystals of a layered network ( 4) comprising the tetracarboxylate of 3 linked by Co(II) ions. The structure of 4 is similar to that of 3, THF exhibiting an AB motif, with two methylimidazole ligands per cobalt atom occupying the remaining volume.

AB - A new tetracarboxylic acid derivative of 9,9'-spirobifluorene (9,9'-spirobifluorene-2,2',7,7'-tetracarboxylic acid (SBFTCA) ( 3)) has been prepared and crystallized as a THF solvate (3 center dot THF). Hydrogen bonding between adjacent molecules of 3 results in a ( 4,4) layer topology and non-interpenetrating AB layer stacking. The topology of 3 gives rise to pores that are occupied by disordered THF molecules. Under hydrothermal conditions, a mixture of 3, methylimidazole, and Co(NO3)(2) gives single crystals of a layered network ( 4) comprising the tetracarboxylate of 3 linked by Co(II) ions. The structure of 4 is similar to that of 3, THF exhibiting an AB motif, with two methylimidazole ligands per cobalt atom occupying the remaining volume.

KW - COORDINATION POLYMERS

KW - ENANTIOSELECTIVE COMPLEXATION

KW - MOLECULAR TECTONICS

KW - DICARBOXYLIC-ACIDS

KW - RATIONAL DESIGN

KW - BUILDING UNITS

KW - FRAMEWORKS

KW - DERIVATIVES

KW - RECOGNITION

KW - COBALT(II)

U2 - 10.1021/cg060007d

DO - 10.1021/cg060007d

M3 - Article

SN - 1528-7483

VL - 6

SP - 1991

EP - 1994

JO - CRYSTAL GROWTH DESIGN

JF - CRYSTAL GROWTH DESIGN

IS - 9

ER -