Ligand exchange reactions within the coordination sphere of a molybdenum eta(2)(4e)-alkyne complex: the formation of an indole in a cascade reaction involving an alkyne and isonitrile ligands

J C  Jeffery; M  Green; J M  Lynam

doi:10.1039/b208867c

Ligand exchange reactions within the coordination sphere of a molybdenum eta(2)(4e)-alkyne complex: the formation of an indole in a cascade reaction involving an alkyne and isonitrile ligands

J C Jeffery, M Green, J M Lynam

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The exchange of phosphorus-containing ligands within the coordination sphere of molybdenum alkyne complexes is shown to be facile, a similar reaction with CNxyl (xyl = C6H3Me2-2,5) results in a remarkable coupling between the alkyne and three isonitrile ligands and C-H bond activation.

Original language	English
Pages (from-to)	3056-3057
Number of pages	2
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/b208867c
Publication status	Published - 2002

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10.1039/b208867c

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title = "Ligand exchange reactions within the coordination sphere of a molybdenum eta(2)(4e)-alkyne complex: the formation of an indole in a cascade reaction involving an alkyne and isonitrile ligands",

abstract = "The exchange of phosphorus-containing ligands within the coordination sphere of molybdenum alkyne complexes is shown to be facile, a similar reaction with CNxyl (xyl = C6H3Me2-2,5) results in a remarkable coupling between the alkyne and three isonitrile ligands and C-H bond activation.",

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journal = "Chemical Communications",

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publisher = "The Royal Society of Chemistry",

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AU - Jeffery, J C

AU - Green, M

AU - Lynam, J M

PY - 2002

Y1 - 2002

N2 - The exchange of phosphorus-containing ligands within the coordination sphere of molybdenum alkyne complexes is shown to be facile, a similar reaction with CNxyl (xyl = C6H3Me2-2,5) results in a remarkable coupling between the alkyne and three isonitrile ligands and C-H bond activation.

AB - The exchange of phosphorus-containing ligands within the coordination sphere of molybdenum alkyne complexes is shown to be facile, a similar reaction with CNxyl (xyl = C6H3Me2-2,5) results in a remarkable coupling between the alkyne and three isonitrile ligands and C-H bond activation.

U2 - 10.1039/b208867c

DO - 10.1039/b208867c

M3 - Article

SN - 1359-7345

SP - 3056

EP - 3057

JO - Chemical Communications

JF - Chemical Communications

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