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From the same journal

Light‐ and Manganese‐Initiated Borylation of Aryl Diazonium Salts: Mechanistic Insight on the Ultrafast Time‐Scale Revealed by Time‐Resolved Spectroscopic Analysis

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JournalChemistry : A European Journal
DateAccepted/In press - 29 Oct 2020
DateE-pub ahead of print (current) - 1 Nov 2020
Number of pages9
Early online date1/11/20
Original languageEnglish

Abstract

Manganese‐mediated borylation of aryl/heteroaryl diazonium salts emerges as a general and versatile synthetic methodology for the synthesis of the corresponding boronate esters. The reaction proved an ideal testing ground for delineating the Mn species responsible for the photochemical reaction processes, i.e. involving either Mn radical or Mn cationic species, which is dependent on the presence of a suitably strong oxidant. Our findings are important for a plethora of processes employing Mn‐containing carbonyl species as initiators and/or catalysts, which have much potential in synthetic applications.

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© 2020 Wiley-VCH GmbH. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

    Research areas

  • Manganese, Boron, Catalysis, radicals, metal cations

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