By the same authors

From the same journal

Liquid-crystalline structure–property relationships in halogen-terminated derivatives of cyanobiphenyl

Research output: Contribution to journalArticlepeer-review

Published copy (DOI)



Publication details

DateE-pub ahead of print - 17 Jun 2014
DatePublished (current) - 2 Nov 2014
Issue number11
Number of pages12
Pages (from-to)1635-1646
Early online date17/06/14
Original languageEnglish


In this article, we report on the liquid-crystalline properties of two series of halogen-terminated cyanobiphenyl-based materials. Unlike other rod-shaped, halogen-terminated materials reported, these materials do not exhibit the smectic A phase and instead only exhibit nematic liquid-crystal mesomorphism. Comparisons between these materials and analogous unsubstituted materials were made, and the relationships between their molecular structures and phase behaviour are discussed with the aid of molecular modelling at the B3LYP/6-31G* level of density functional theory.

    Research areas

  • cyanobiphenyl, density functional theory, halogen terminated, smectic A, smectic A stabilisation


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