By the same authors

From the same journal

Loss of internal 1->6 substituted monosaccharide residues from underivatized and per-O-methylated trisaccharides

Research output: Contribution to journalArticle

Author(s)

Department/unit(s)

Publication details

JournalJOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
DatePublished - Jan 1997
Issue number1
Volume8
Number of pages7
Pages (from-to)43-49
Original languageEnglish

Abstract

The fragmentation behavior of [M + H](+) ions of a series of underivatized and per-O-methylated trisaccharides having 1 --> 6 linked residues, of which one or two is a deoxy-fluoro or deoxy residue and thus has a unique mass, has been studied by using collision-induced dissociation fast-atom bombardment mass spectrometry. In addition to the usual fragment ions resulting from glycosidic bond cleavage, fragment ions were observed which must have been generated following an unusual rearrangement process which can be rationalized in terms of the loss of an internal monosaccharide residue. (C) 1997 American Society for Mass Spectrometry

    Research areas

  • FAST-ATOM-BOMBARDMENT, TANDEM MASS-SPECTROMETRY, BETA-GLYCOSIDES, INDUCED DISSOCIATION, OLIGOSACCHARIDE CHARACTERIZATION, (1->6)-BETA-D-GALACTOOLIGOSACCHARIDES, FAB, O-(3-DEOXY-3-FLUORO-BETA-D-GALACTOPYRANOSYL)-(1->6)-O-BETA-D-GALACTOPYRANOSYL-(., (1->6)-BETA-D-GALACTO-OLIGOSACCHARIDES, SPECTRA

Discover related content

Find related publications, people, projects, datasets and more using interactive charts.

View graph of relations