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Manganese(I)-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination

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Manganese(I)-Catalyzed C−H Activation : The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination. / Yahaya, Nasiru P.; Appleby, Kate M.; Teh, Magdalene; Wagner, Conrad; Troschke, Erik; Bray, Joshua T W; Duckett, Simon B.; Hammarback, L. Anders; Ward, Jonathan S.; Milani, Jessica; Pridmore, Natalie E.; Whitwood, Adrian C.; Lynam, Jason M.; Fairlamb, Ian J S.

In: Angewandte Chemie International Edition, Vol. 55, No. 40, 26.09.2016, p. 12455-12459.

Research output: Contribution to journalArticle

Harvard

Yahaya, NP, Appleby, KM, Teh, M, Wagner, C, Troschke, E, Bray, JTW, Duckett, SB, Hammarback, LA, Ward, JS, Milani, J, Pridmore, NE, Whitwood, AC, Lynam, JM & Fairlamb, IJS 2016, 'Manganese(I)-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination', Angewandte Chemie International Edition, vol. 55, no. 40, pp. 12455-12459. https://doi.org/10.1002/anie.201606236

APA

Yahaya, N. P., Appleby, K. M., Teh, M., Wagner, C., Troschke, E., Bray, J. T. W., ... Fairlamb, I. J. S. (2016). Manganese(I)-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination. Angewandte Chemie International Edition, 55(40), 12455-12459. https://doi.org/10.1002/anie.201606236

Vancouver

Yahaya NP, Appleby KM, Teh M, Wagner C, Troschke E, Bray JTW et al. Manganese(I)-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination. Angewandte Chemie International Edition. 2016 Sep 26;55(40):12455-12459. https://doi.org/10.1002/anie.201606236

Author

Yahaya, Nasiru P. ; Appleby, Kate M. ; Teh, Magdalene ; Wagner, Conrad ; Troschke, Erik ; Bray, Joshua T W ; Duckett, Simon B. ; Hammarback, L. Anders ; Ward, Jonathan S. ; Milani, Jessica ; Pridmore, Natalie E. ; Whitwood, Adrian C. ; Lynam, Jason M. ; Fairlamb, Ian J S. / Manganese(I)-Catalyzed C−H Activation : The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination. In: Angewandte Chemie International Edition. 2016 ; Vol. 55, No. 40. pp. 12455-12459.

Bibtex - Download

@article{5fbfc8018646415da44f1cf5e5d4de3f,
title = "Manganese(I)-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination",
abstract = "Manganese-catalyzed C−H bond activation chemistry is emerging as a powerful and complementary method for molecular functionalization. A highly reactive seven-membered MnIintermediate is detected and characterized that is effective for H-transfer or reductive elimination to deliver alkenylated or pyridinium products, respectively. The two pathways are determined at MnIby judicious choice of an electron-deficient 2-pyrone substrate containing a 2-pyridyl directing group, which undergoes regioselective C−H bond activation, serving as a valuable system for probing the mechanistic features of Mn C−H bond activation chemistry.",
keywords = "catalysis, C−H activation, functionalization, manganese, sustainability",
author = "Yahaya, {Nasiru P.} and Appleby, {Kate M.} and Magdalene Teh and Conrad Wagner and Erik Troschke and Bray, {Joshua T W} and Duckett, {Simon B.} and Hammarback, {L. Anders} and Ward, {Jonathan S.} and Jessica Milani and Pridmore, {Natalie E.} and Whitwood, {Adrian C.} and Lynam, {Jason M.} and Fairlamb, {Ian J S}",
note = "{\circledC} 2016, The Authors.",
year = "2016",
month = "9",
day = "26",
doi = "10.1002/anie.201606236",
language = "English",
volume = "55",
pages = "12455--12459",
journal = "Angewandte Chemie International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "40",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Manganese(I)-Catalyzed C−H Activation

T2 - Angewandte Chemie International Edition

AU - Yahaya, Nasiru P.

AU - Appleby, Kate M.

AU - Teh, Magdalene

AU - Wagner, Conrad

AU - Troschke, Erik

AU - Bray, Joshua T W

AU - Duckett, Simon B.

AU - Hammarback, L. Anders

AU - Ward, Jonathan S.

AU - Milani, Jessica

AU - Pridmore, Natalie E.

AU - Whitwood, Adrian C.

AU - Lynam, Jason M.

AU - Fairlamb, Ian J S

N1 - © 2016, The Authors.

PY - 2016/9/26

Y1 - 2016/9/26

N2 - Manganese-catalyzed C−H bond activation chemistry is emerging as a powerful and complementary method for molecular functionalization. A highly reactive seven-membered MnIintermediate is detected and characterized that is effective for H-transfer or reductive elimination to deliver alkenylated or pyridinium products, respectively. The two pathways are determined at MnIby judicious choice of an electron-deficient 2-pyrone substrate containing a 2-pyridyl directing group, which undergoes regioselective C−H bond activation, serving as a valuable system for probing the mechanistic features of Mn C−H bond activation chemistry.

AB - Manganese-catalyzed C−H bond activation chemistry is emerging as a powerful and complementary method for molecular functionalization. A highly reactive seven-membered MnIintermediate is detected and characterized that is effective for H-transfer or reductive elimination to deliver alkenylated or pyridinium products, respectively. The two pathways are determined at MnIby judicious choice of an electron-deficient 2-pyrone substrate containing a 2-pyridyl directing group, which undergoes regioselective C−H bond activation, serving as a valuable system for probing the mechanistic features of Mn C−H bond activation chemistry.

KW - catalysis

KW - C−H activation

KW - functionalization

KW - manganese

KW - sustainability

UR - http://www.scopus.com/inward/record.url?scp=84987653166&partnerID=8YFLogxK

U2 - 10.1002/anie.201606236

DO - 10.1002/anie.201606236

M3 - Article

VL - 55

SP - 12455

EP - 12459

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 40

ER -