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From the same journal

Measurement of the first ionization potential of astatine by laser ionization spectroscopy

Research output: Contribution to journalArticle


  • S. Rothe
  • Andrei Andreyev
  • S. Antalic
  • A Borschevsky
  • L Capponi
  • T. E. Cocolios
  • H. De Witte
  • E Eliav
  • D. V. Fedorov
  • V N Fedosseev
  • D.A. Fink
  • S. Fritzsche
  • L. Ghys
  • M. Huyse
  • N. Imai
  • U. Kaldor
  • Yuri Kudryavtsev
  • U Koster
  • J. F. W. Lane
  • J. Lassen


Publication details

JournalNature Communications
DateE-pub ahead of print - 14 May 2013
DatePublished (current) - 2013
Number of pages6
Pages (from-to)1-6
Early online date14/05/13
Original languageEnglish


The radioactive element astatine exists only in trace amounts in nature. Its properties can therefore only be explored by study of the minute quantities of artificially produced isotopes or by performing theoretical calculations. One of the most important properties influencing the chemical behaviour is the energy required to remove one electron from the valence shell, referred to as the ionization potential. Here we use laser spectroscopy to probe the optical spectrum of astatine near the ionization threshold. The observed series of Rydberg states enabled the first determination of the ionization potential of the astatine atom, 9.31751(8) eV. New ab initio calculations are performed to support the experimental result. The measured value serves as a benchmark for quantum chemistry calculations of the properties of astatine as well as for the theoretical prediction of the ionization potential of superheavy element 117, the heaviest homologue of astatine.

    Research areas

  • Physical sciences, Atomic and molecular physics

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