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Mechanistic insight into proton-coupled mixed valency

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Mechanistic insight into proton-coupled mixed valency. / Wilkinson, Luke Alexander; Vincent, Kevin ; Meijer, Anthony; Patmore, Nathan .

In: Chemical communications, Vol. 52, No. 1, 2016, p. 100-103.

Research output: Contribution to journalArticle

Harvard

Wilkinson, LA, Vincent, K, Meijer, A & Patmore, N 2016, 'Mechanistic insight into proton-coupled mixed valency', Chemical communications, vol. 52, no. 1, pp. 100-103. https://doi.org/10.1039/C5CC07101A

APA

Wilkinson, L. A., Vincent, K., Meijer, A., & Patmore, N. (2016). Mechanistic insight into proton-coupled mixed valency. Chemical communications, 52(1), 100-103. https://doi.org/10.1039/C5CC07101A

Vancouver

Wilkinson LA, Vincent K, Meijer A, Patmore N. Mechanistic insight into proton-coupled mixed valency. Chemical communications. 2016;52(1):100-103. https://doi.org/10.1039/C5CC07101A

Author

Wilkinson, Luke Alexander ; Vincent, Kevin ; Meijer, Anthony ; Patmore, Nathan . / Mechanistic insight into proton-coupled mixed valency. In: Chemical communications. 2016 ; Vol. 52, No. 1. pp. 100-103.

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@article{f335411c8f814827b55562f8060fc3b9,
title = "Mechanistic insight into proton-coupled mixed valency",
abstract = "Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2+ (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands. Spectroelectrochemical studies suggest that ET is slower than 109 s−1. The mechanism has been probed using DFT calculations, which show that proton transfer induces a larger dipole in the molecule resulting in ET.",
author = "Wilkinson, {Luke Alexander} and Kevin Vincent and Anthony Meijer and Nathan Patmore",
year = "2016",
doi = "10.1039/C5CC07101A",
language = "English",
volume = "52",
pages = "100--103",
journal = "Chemical communications",
issn = "1359-7345",
publisher = "The Royal Society of Chemistry",
number = "1",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Mechanistic insight into proton-coupled mixed valency

AU - Wilkinson, Luke Alexander

AU - Vincent, Kevin

AU - Meijer, Anthony

AU - Patmore, Nathan

PY - 2016

Y1 - 2016

N2 - Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2+ (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands. Spectroelectrochemical studies suggest that ET is slower than 109 s−1. The mechanism has been probed using DFT calculations, which show that proton transfer induces a larger dipole in the molecule resulting in ET.

AB - Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2+ (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands. Spectroelectrochemical studies suggest that ET is slower than 109 s−1. The mechanism has been probed using DFT calculations, which show that proton transfer induces a larger dipole in the molecule resulting in ET.

U2 - 10.1039/C5CC07101A

DO - 10.1039/C5CC07101A

M3 - Article

VL - 52

SP - 100

EP - 103

JO - Chemical communications

JF - Chemical communications

SN - 1359-7345

IS - 1

ER -