Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

Marco Conte; Yun Ma; Colin Loyns; Peter Price; David Rippon; Victor Chechik

doi:10.1039/b905893a

Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

Marco Conte, Yun Ma, Colin Loyns, Peter Price, David Rippon, Victor Chechik

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Convolution-based fitting of EPR spectra makes it possible to simultaneously determine concentrations of TEMPO and oxygen in TEMPO-inhibited polymerisations and autoxidations; this method is useful for understanding the chemistry of inhibitor mixtures.

Original language	English
Pages (from-to)	2685-2687
Number of pages	3
Journal	Organic and Biomolecular Chemistry
Volume	7
Issue number	13
DOIs	https://doi.org/10.1039/b905893a
Publication status	Published - 2009

Keywords

AUTOXIDATION
CONSUMPTION
STYRENE

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10.1039/b905893a

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@article{42162040afc143a491ec47bc4ef1e352,

title = "Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR",

abstract = "Convolution-based fitting of EPR spectra makes it possible to simultaneously determine concentrations of TEMPO and oxygen in TEMPO-inhibited polymerisations and autoxidations; this method is useful for understanding the chemistry of inhibitor mixtures.",

keywords = "AUTOXIDATION, CONSUMPTION, STYRENE",

author = "Marco Conte and Yun Ma and Colin Loyns and Peter Price and David Rippon and Victor Chechik",

year = "2009",

doi = "10.1039/b905893a",

language = "English",

volume = "7",

pages = "2685--2687",

journal = "Organic and Biomolecular Chemistry",

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publisher = "The Royal Society of Chemistry",

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TY - JOUR

T1 - Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

AU - Conte, Marco

AU - Ma, Yun

AU - Loyns, Colin

AU - Price, Peter

AU - Rippon, David

AU - Chechik, Victor

PY - 2009

Y1 - 2009

N2 - Convolution-based fitting of EPR spectra makes it possible to simultaneously determine concentrations of TEMPO and oxygen in TEMPO-inhibited polymerisations and autoxidations; this method is useful for understanding the chemistry of inhibitor mixtures.

AB - Convolution-based fitting of EPR spectra makes it possible to simultaneously determine concentrations of TEMPO and oxygen in TEMPO-inhibited polymerisations and autoxidations; this method is useful for understanding the chemistry of inhibitor mixtures.

KW - AUTOXIDATION

KW - CONSUMPTION

KW - STYRENE

UR - http://www.scopus.com/inward/record.url?scp=67649099984&partnerID=8YFLogxK

U2 - 10.1039/b905893a

DO - 10.1039/b905893a

M3 - Article

SN - 1477-0520

VL - 7

SP - 2685

EP - 2687

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 13

ER -

Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

Abstract

Keywords

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