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Mesomorphism of ortho-metallated imine complexes of the β-diketonatoplatinum(II) fragment. Crystal and molecular structure of three platinum imine complexes

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JournalLIQUID CRYSTALS
DatePublished - 1 Dec 2007
Issue number12
Volume34
Number of pages10
Pages (from-to)1463-1472
Original languageEnglish

Abstract

The synthesis of a series of ortho-metallated Pt imine complexes bound to a range of β-diketonato ligands is described and the crystal structures of three are reported; two show unusually short F⋯F contacts in the solid state. All but one of the new complexes show liquid crystal mesophases and the thermal behaviour was studied using a combination of optical microscopy and differential scanning calorimetry. The mesomorphism is compared with that of analogous palladium complexes reported previously.

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