Meta-arylation of calixarenes using organomercurial chemistry

Petr Slavík; Karolína Flídrová; Hana Dvořáková; Václav Eigner; Pavel Lhoták

doi:10.1039/c3ob41085d

Meta-arylation of calixarenes using organomercurial chemistry

Petr Slavík, Karolína Flídrová, Hana Dvořáková, Václav Eigner, Pavel Lhoták^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A direct mercuration reaction combined with a subsequent Pd-catalyzed arylation was used to introduce the aryl moiety into the meta position of the calix[4]arene skeleton. The application of organomercurial intermediates thus allows the straightforward formation of meta-aryl-substituted derivatives representing a unique substitution pattern in calixarene chemistry.

Original language	English
Pages (from-to)	5528-5534
Number of pages	7
Journal	Organic and Biomolecular Chemistry
Volume	11
Issue number	33
DOIs	https://doi.org/10.1039/c3ob41085d
Publication status	Published - 1 Jan 2013

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AU - Slavík, Petr

AU - Flídrová, Karolína

AU - Dvořáková, Hana

AU - Eigner, Václav

AU - Lhoták, Pavel

PY - 2013/1/1

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AB - A direct mercuration reaction combined with a subsequent Pd-catalyzed arylation was used to introduce the aryl moiety into the meta position of the calix[4]arene skeleton. The application of organomercurial intermediates thus allows the straightforward formation of meta-aryl-substituted derivatives representing a unique substitution pattern in calixarene chemistry.

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JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

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Meta-arylation of calixarenes using organomercurial chemistry

Abstract

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