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From the same journal

Meta-Bridged calix[4]arenes: A straightforward synthesis via organomercurial chemistry

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Published copy (DOI)

Author(s)

  • Karolína Flídrová
  • Petr Slavík
  • Václav Eigner
  • Hana Dvořáková
  • Pavel Lhoták

Department/unit(s)

Publication details

JournalChemical Communications
DatePublished - 4 Aug 2013
Issue number60
Volume49
Number of pages3
Pages (from-to)6749-6751
Original languageEnglish

Abstract

The regioselective mercuration of tetraalkylated calix[4]arenes with Hg(OCOCF3)2 leads to the formation of meta-substituted products which enabled Pd-catalysed intramolecular bridging within the calixarene skeleton. Bridged derivatives represent a completely novel substitution pattern in calixarene chemistry with extremely distorted cavities and possible applications in supramolecular chemistry.

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