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α-methoxyketone synthesis via ketone homologation: ZrCl 4-mediated hydroxy sulfone rearrangements

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JournalJournal of the Chemical Society, Chemical Communications
DatePublished - 1 Dec 1994
Issue number19
Number of pages2
Pages (from-to)2289-2290
Original languageEnglish

Abstract

The adducts between ketones and the anion derived from [(methoxymethyl) sulfonyl]benzene undergo efficient, regioselective rearrangement to give α-methoxyketones when treated with ZrCl4 and HfCl4; this new procedure allows the sulfone-mediated homologation methodology to be applied to monocyclic and acyclic ketones.

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