Microwave-Assisted Immobilization of Manganese Salen Complexes: Increased Activity and Chemoselectivity in Catalytic Epoxidation

Ana Rosa Silva; Vitaly Budarin; James H. Clark

doi:10.1002/cctc.201200376

Microwave-Assisted Immobilization of Manganese Salen Complexes: Increased Activity and Chemoselectivity in Catalytic Epoxidation

Ana Rosa Silva^*, Vitaly Budarin, James H. Clark

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

An anchor into the microwaves: A directing effect on the orientation of the manganese(III) salen complexes towards the activated carbon surface was activated by using microwave-assisted anchoring. The immobilization procedure is simple, energy efficient, and fast. The resulting materials are unusually active and selective heterogeneous catalysts for the epoxidation of styrene.

Original language	English
Pages (from-to)	895-898
Number of pages	4
Journal	ChemCatChem
Volume	5
Issue number	4
Early online date	5 Sept 2012
DOIs	https://doi.org/10.1002/cctc.201200376
Publication status	Published - Apr 2013

Keywords

Epoxidation
Heterogeneous catalysis
Immobilization
Microwave chemistry
Surface chemistry

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10.1002/cctc.201200376

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abstract = "An anchor into the microwaves: A directing effect on the orientation of the manganese(III) salen complexes towards the activated carbon surface was activated by using microwave-assisted anchoring. The immobilization procedure is simple, energy efficient, and fast. The resulting materials are unusually active and selective heterogeneous catalysts for the epoxidation of styrene.",

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AU - Budarin, Vitaly

AU - Clark, James H.

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AB - An anchor into the microwaves: A directing effect on the orientation of the manganese(III) salen complexes towards the activated carbon surface was activated by using microwave-assisted anchoring. The immobilization procedure is simple, energy efficient, and fast. The resulting materials are unusually active and selective heterogeneous catalysts for the epoxidation of styrene.

KW - Epoxidation

KW - Heterogeneous catalysis

KW - Immobilization

KW - Microwave chemistry

KW - Surface chemistry

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Microwave-Assisted Immobilization of Manganese Salen Complexes: Increased Activity and Chemoselectivity in Catalytic Epoxidation

Abstract

Keywords

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