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Mixed valency in hydrogen bonded ‘dimers of dimers’

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Mixed valency in hydrogen bonded ‘dimers of dimers’. / Wilkinson, Luke Alexander; McNeill, Laura; Meijer, Anthony; Patmore, Nathan.

In: Journal of the American Chemical Society, Vol. 135, No. 5, 2013, p. 1723-1726.

Research output: Contribution to journalArticlepeer-review

Harvard

Wilkinson, LA, McNeill, L, Meijer, A & Patmore, N 2013, 'Mixed valency in hydrogen bonded ‘dimers of dimers’', Journal of the American Chemical Society, vol. 135, no. 5, pp. 1723-1726. https://doi.org/10.1021/ja312176x

APA

Wilkinson, L. A., McNeill, L., Meijer, A., & Patmore, N. (2013). Mixed valency in hydrogen bonded ‘dimers of dimers’. Journal of the American Chemical Society, 135(5), 1723-1726. https://doi.org/10.1021/ja312176x

Vancouver

Wilkinson LA, McNeill L, Meijer A, Patmore N. Mixed valency in hydrogen bonded ‘dimers of dimers’. Journal of the American Chemical Society. 2013;135(5):1723-1726. https://doi.org/10.1021/ja312176x

Author

Wilkinson, Luke Alexander ; McNeill, Laura ; Meijer, Anthony ; Patmore, Nathan. / Mixed valency in hydrogen bonded ‘dimers of dimers’. In: Journal of the American Chemical Society. 2013 ; Vol. 135, No. 5. pp. 1723-1726.

Bibtex - Download

@article{26e52c5badb34c718ce3a96f77f05561,
title = "Mixed valency in hydrogen bonded {\textquoteleft}dimers of dimers{\textquoteright}",
abstract = "Dimolybdenum quadruply bonded compounds containing a pendant lactam functional group form self-complementary hydrogen bonded {\textquoteleft}dimers of dimers{\textquoteright} in the solid-state and CH2Cl2 solutions. Electrochemical studies in CH2Cl2 show two consecutive one-electron redox processes corresponding to oxidation of the Mo24+ cores. Spectroelectrochemical studies on the {\textquoteleft}dimers of dimers{\textquoteright} show no evidence of intervalence charge transfer bands in the mixed valence radical cations formed by one-electron oxidation, indicating that they are examples of proton-coupled mixed valency.",
author = "Wilkinson, {Luke Alexander} and Laura McNeill and Anthony Meijer and Nathan Patmore",
year = "2013",
doi = "10.1021/ja312176x",
language = "English",
volume = "135",
pages = "1723--1726",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "5",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Mixed valency in hydrogen bonded ‘dimers of dimers’

AU - Wilkinson, Luke Alexander

AU - McNeill, Laura

AU - Meijer, Anthony

AU - Patmore, Nathan

PY - 2013

Y1 - 2013

N2 - Dimolybdenum quadruply bonded compounds containing a pendant lactam functional group form self-complementary hydrogen bonded ‘dimers of dimers’ in the solid-state and CH2Cl2 solutions. Electrochemical studies in CH2Cl2 show two consecutive one-electron redox processes corresponding to oxidation of the Mo24+ cores. Spectroelectrochemical studies on the ‘dimers of dimers’ show no evidence of intervalence charge transfer bands in the mixed valence radical cations formed by one-electron oxidation, indicating that they are examples of proton-coupled mixed valency.

AB - Dimolybdenum quadruply bonded compounds containing a pendant lactam functional group form self-complementary hydrogen bonded ‘dimers of dimers’ in the solid-state and CH2Cl2 solutions. Electrochemical studies in CH2Cl2 show two consecutive one-electron redox processes corresponding to oxidation of the Mo24+ cores. Spectroelectrochemical studies on the ‘dimers of dimers’ show no evidence of intervalence charge transfer bands in the mixed valence radical cations formed by one-electron oxidation, indicating that they are examples of proton-coupled mixed valency.

U2 - 10.1021/ja312176x

DO - 10.1021/ja312176x

M3 - Article

VL - 135

SP - 1723

EP - 1726

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 5

ER -