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mu(2)-Alkyne dicobalt(0)hexacarbonyl complexes as carbon monoxide-releasing molecules (CO-RMs): probing the release mechanism

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JournalDalton Transactions
DatePublished - 2009
Issue number19
Volume38
Number of pages4
Pages (from-to)3653-3656
Original languageEnglish

Abstract

The first carbon monoxide-releasing molecules (CO-RMs) based on mu(2)-alkyne dicobalt(0)hexacarbonyl complexes are reported. The alkyne substituents significantly affect the rate of CO-release, cytotoxicity and cell viability. Mechanistic studies provide insight into the CO-RM activation pathways.

    Research areas

  • COBALT-ALKYNE COMPLEXES, METAL-CARBONYLS, CELLULAR UPTAKE, CYTOTOXICITY, MODULATION, CHEMISTRY

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