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mu(2)-Alkyne dicobalt(0)hexacarbonyl complexes as carbon monoxide-releasing molecules (CO-RMs): probing the release mechanism
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| Journal | Dalton Transactions |
|---|---|
| Date | Published - 2009 |
| Issue number | 19 |
| Volume | 38 |
| Number of pages | 4 |
| Pages (from-to) | 3653-3656 |
| Original language | English |
Abstract
The first carbon monoxide-releasing molecules (CO-RMs) based on mu(2)-alkyne dicobalt(0)hexacarbonyl complexes are reported. The alkyne substituents significantly affect the rate of CO-release, cytotoxicity and cell viability. Mechanistic studies provide insight into the CO-RM activation pathways.
- COBALT-ALKYNE COMPLEXES, METAL-CARBONYLS, CELLULAR UPTAKE, CYTOTOXICITY, MODULATION, CHEMISTRY
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