mu(2)-Alkyne dicobalt(0)hexacarbonyl complexes as carbon monoxide-releasing molecules (CO-RMs): probing the release mechanism

By the same authors

Manganese-Mediated C–H Bond Activation of Fluorinated Aromatics and the ortho-Fluorine Effect: Kinetic Analysis by In Situ Infrared Spectroscopic Analysis and Time-Resolved Methods
Hammarback, L. A., Bishop, A. L., Jordan, C., Athavan, G., Eastwood, J. B., Burden, T. J., Bray, J. T. W., Clarke, F., Robinson, A., Krieger, J. P., Whitwood, A., Clark, I. P., Towrie, M., Lynam, J. M. & Fairlamb, I. J. S., 21 Jan 2022
Article in ACS Catalysis
Manganese-catalyzed C-H bond activation and functionalization, from mechanism to applications: CHF-0192
Burden, T., Eastwood, J., Fairlamb, I. J. S. & Lynam, J. M., 1 Nov 2021, (Accepted/In press) Handbook of CH-Functionalization. Wiley, p. 1-29 29 p.
Research output: Chapter in Book/Report/Conference proceeding › Chapter
Pd-Catalysed carbonylative Suzuki-Miyaura cross-couplings using Fe(CO)₅under mild conditions: generation of a highly active, recyclable and scalable ‘Pd-Fe’ nanocatalyst
Zhu, Z., Wang, Z., Jian, Y., Sun, H., Zhang, G., Lynam, J. M., McElroy, C. R., Burden, T. J., Inight, R. L., Fairlamb, I. J. S., Zhang, W. & Gao, Z., 21 Jan 2021
Article in Green Chemistry
Direct Observation of the Microscopic Reverse of the Ubiquitous Concerted Metalation Deprotonation Step in C-H Bond Activation Catalysis
Hammarback, L. A., Aucott, B. J., Bray, J. T. W., Towrie, M., Robinson, A., Fairlamb, I. J. S. & Lynam, J. M., 11 Jan 2021
Article in Journal of the American Chemical Society
Light‐ and Manganese‐Initiated Borylation of Aryl Diazonium Salts: Mechanistic Insight on the Ultrafast Time‐Scale Revealed by Time‐Resolved Spectroscopic Analysis
Firth, J., Hammarback, A., Burden, T., Eastwood, J., Donald, J. R., Horbaczewskyj, C., McRobie, M., Tramaseur, A., Clark, I. P., Towrie, M., Robinson, A., Robinson, A., Krieger, J-P., Lynam, J. M. & Fairlamb, I. J. S., 1 Nov 2020, (E-pub ahead of print)
Article in Chemistry : A European Journal

From the same journal

MicroED Characterization of a Robust Cationic -Alkane Complex Stabilized by the [B(3,5-(SF5)2C6H3)4]– Anion, via On-Grid Solid/Gas Single-Crystal to Single-Crystal Reactivity
Weller, A., Doyle, L. R., Thompson, E., Burnage, A. L., Whitwood, A. C., Jenkins, H. T. & Macgregor, S. A., 3 Feb 2022, (E-pub ahead of print)
Article in Dalton Transactions
Exploring the hyperpolarisation of EGTA-based ligands using SABRE
Tickner, B., Borozdina, Y., Duckett, S. B. & Angelovski, G., 22 Jan 2021, (E-pub ahead of print)
Article in Dalton Transactions
Structural analysis of five-coordinate aluminium(salen) complexes and its relationship to their catalytic activity
Fish, H., Hart, S., Lamb, K. J., North, M., Quek, S. C. Z., Whitwood, A. C., Woods, B. & Wu, X., 14 Jan 2021
Article in Dalton Transactions
Cytotoxic (cis,cis-1,3,5-triaminocyclohexane)ruthenium(II)–diphosphine complexes; evidence for covalent binding and intercalation with DNA
Wise, D. E., Gamble, A. J., Arkawazi, S., Walton, P. H., Galan, M. C., O’Hagan, M. P., Hogg, K., Marrison, J., O'Toole, P. J., Sparkes, H. A., Lynam, J. M. & Pringle, P. G., 30 Sep 2020, (E-pub ahead of print)
Article in Dalton Transactions
Correction: Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(i) carbonyl complex (Dalton Trans. (2020) DOI: 10.1039/c9dt04878b)
Eastwood, J. B., Hammarback, L. A., McRobie, M. T., Clark, I. P., Towrie, M., Fairlamb, I. J. S. & Lynam, J. M., 7 Jun 2020
Comment/debate in Dalton Transactions

From the same journal

Dalton Transactions (Journal)
Derek Alan Wann (Reviewer)
2008 → …
Activity: Publication peer-review and editorial work › Journal peer review

Research output: Contribution to journal › Article › peer-review

Published copy (DOI)

10.1039/b904627p

Author(s)

Anthony J. Atkin
Sophie Williams
Philip Sawle
Roberto Motterlini
Jason M. Lynam
Ian J. S. Fairlamb

Department/unit(s)

Chemistry

Publication details

Journal	Dalton Transactions
Date	Published - 2009
Issue number	19
Volume	38
Number of pages	4
Pages (from-to)	3653-3656
Original language	English

Abstract

The first carbon monoxide-releasing molecules (CO-RMs) based on mu(2)-alkyne dicobalt(0)hexacarbonyl complexes are reported. The alkyne substituents significantly affect the rate of CO-release, cytotoxicity and cell viability. Mechanistic studies provide insight into the CO-RM activation pathways.

Research areas

COBALT-ALKYNE COMPLEXES, METAL-CARBONYLS, CELLULAR UPTAKE, CYTOTOXICITY, MODULATION, CHEMISTRY

Discover related content

Find related publications, people, projects, datasets and more using interactive charts.

View graph of relations

York staff: edit these data

The York Research Database

By the same authors

Manganese-Mediated C–H Bond Activation of Fluorinated Aromatics and the ortho-Fluorine Effect: Kinetic Analysis by In Situ Infrared Spectroscopic Analysis and Time-Resolved Methods

Manganese-catalyzed C-H bond activation and functionalization, from mechanism to applications: CHF-0192

Pd-Catalysed carbonylative Suzuki-Miyaura cross-couplings using Fe(CO)₅under mild conditions: generation of a highly active, recyclable and scalable ‘Pd-Fe’ nanocatalyst

Direct Observation of the Microscopic Reverse of the Ubiquitous Concerted Metalation Deprotonation Step in C-H Bond Activation Catalysis

Light‐ and Manganese‐Initiated Borylation of Aryl Diazonium Salts: Mechanistic Insight on the Ultrafast Time‐Scale Revealed by Time‐Resolved Spectroscopic Analysis

From the same journal

MicroED Characterization of a Robust Cationic -Alkane Complex Stabilized by the [B(3,5-(SF5)2C6H3)4]– Anion, via On-Grid Solid/Gas Single-Crystal to Single-Crystal Reactivity

Exploring the hyperpolarisation of EGTA-based ligands using SABRE

Structural analysis of five-coordinate aluminium(salen) complexes and its relationship to their catalytic activity

Cytotoxic (cis,cis-1,3,5-triaminocyclohexane)ruthenium(II)–diphosphine complexes; evidence for covalent binding and intercalation with DNA

Correction: Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(i) carbonyl complex (Dalton Trans. (2020) DOI: 10.1039/c9dt04878b)

From the same journal

Dalton Transactions (Journal)

mu(2)-Alkyne dicobalt(0)hexacarbonyl complexes as carbon monoxide-releasing molecules (CO-RMs): probing the release mechanism

Links

Published copy (DOI)

Author(s)

Department/unit(s)

Publication details

Abstract

Research areas

Discover related content