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Multinuclear NMR studies of the fluoride-uracil complex

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JournalSpectrochimica Acta Part A: Molecular Spectroscopy
DatePublished - 1 Jan 1982
Issue number10
Volume38
Number of pages4
Pages (from-to)1101-1104
Original languageEnglish

Abstract

1H, 19F and 15N NMR spectroscopy has been carried out on the soluble hydrogen bonded complex (CH3CH2)4N+F- (uracil). The studies suggest that deprotonation of the uracil does not occur and that in a medium dielectric constant solvent, hydrogen bonding occurs at the N(1)H site. Spectroscopic monitoring of the controlled thermal decomposition of the complex shows that complex breakdown occurs via the uracil anion, HF-2 and neutral uracil.

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