'Naked fluoride' masked: N.m.r. evidence for tight ion pairs in KF-crown ether

Jack M. Miller^*, James H. Clark

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

¹⁹F N.m.r. spectra of solutions of KF-18-crown-6 in a variety of organic solvents show ca. 6 kHz line widths essentially indistinguishable from those of solid KF suggesting tight ion pairs or higher aggregates in solution.

Original language	English
Pages (from-to)	1318-1319
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/C39820001318
Publication status	Published - 1 Jan 1982

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10.1039/C39820001318

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Cite this

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title = "'Naked fluoride' masked: N.m.r. evidence for tight ion pairs in KF-crown ether",

abstract = "19F N.m.r. spectra of solutions of KF-18-crown-6 in a variety of organic solvents show ca. 6 kHz line widths essentially indistinguishable from those of solid KF suggesting tight ion pairs or higher aggregates in solution.",

author = "Miller, {Jack M.} and Clark, {James H.}",

year = "1982",

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AB - 19F N.m.r. spectra of solutions of KF-18-crown-6 in a variety of organic solvents show ca. 6 kHz line widths essentially indistinguishable from those of solid KF suggesting tight ion pairs or higher aggregates in solution.

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