Novel tandem conjugate addition-Ramberg-Backlund rearrangements

P  Evans; R J K  Taylor

Novel tandem conjugate addition-Ramberg-Backlund rearrangements

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A novel tandem process is reported for the preparation of allylic amines, ethers and sulfides from alpha-bromo-alpha,beta-unsaturated sulfones; this process is believed to proceed via an initial conjugate addition followed by proton exchange and Ramberg-Backlund rearrangement.

Original language	English
Pages (from-to)	1043-1044
Number of pages	2
Journal	Synlett
Issue number	9
Publication status	Published - Sept 1997

Keywords

Michael-induced Ramherg-Backlund (MIRB) rearrangements
vinyl sulfones
allylic amines
allylic ethers
allylic sulfides
RADICAL CYCLIZATION
CHEMISTRY
SULFONES

Cite this

@article{1bb3162e4e81468eb9100cf9afabc834,

title = "Novel tandem conjugate addition-Ramberg-Backlund rearrangements",

abstract = "A novel tandem process is reported for the preparation of allylic amines, ethers and sulfides from alpha-bromo-alpha,beta-unsaturated sulfones; this process is believed to proceed via an initial conjugate addition followed by proton exchange and Ramberg-Backlund rearrangement.",

keywords = "Michael-induced Ramherg-Backlund (MIRB) rearrangements, vinyl sulfones, allylic amines, allylic ethers, allylic sulfides, RADICAL CYCLIZATION, CHEMISTRY, SULFONES",

author = "P Evans and Taylor, {R J K}",

year = "1997",

month = sep,

language = "English",

pages = "1043--1044",

journal = "Synlett",

issn = "1437-2096",

publisher = "Georg Thieme Verlag",

number = "9",

}

TY - JOUR

T1 - Novel tandem conjugate addition-Ramberg-Backlund rearrangements

AU - Evans, P

AU - Taylor, R J K

PY - 1997/9

Y1 - 1997/9

N2 - A novel tandem process is reported for the preparation of allylic amines, ethers and sulfides from alpha-bromo-alpha,beta-unsaturated sulfones; this process is believed to proceed via an initial conjugate addition followed by proton exchange and Ramberg-Backlund rearrangement.

AB - A novel tandem process is reported for the preparation of allylic amines, ethers and sulfides from alpha-bromo-alpha,beta-unsaturated sulfones; this process is believed to proceed via an initial conjugate addition followed by proton exchange and Ramberg-Backlund rearrangement.

KW - Michael-induced Ramherg-Backlund (MIRB) rearrangements

KW - vinyl sulfones

KW - allylic amines

KW - allylic ethers

KW - allylic sulfides

KW - RADICAL CYCLIZATION

KW - CHEMISTRY

KW - SULFONES

M3 - Article

SN - 1437-2096

SP - 1043

EP - 1044

JO - Synlett

JF - Synlett

IS - 9

ER -