ORGANOMETALLIC ADDITIONS TO PROTECTED QUINONE BIS-EPOXIDES AND QUINONE MONOACETALS - SYNTHESIS OF THE ARANOROSIN NUCLEUS

A  MCKILLOP; R J K  TAYLOR; R J  WATSON; N  LEWIS

ORGANOMETALLIC ADDITIONS TO PROTECTED QUINONE BIS-EPOXIDES AND QUINONE MONOACETALS - SYNTHESIS OF THE ARANOROSIN NUCLEUS

A MCKILLOP, R J K TAYLOR, R J WATSON, N LEWIS

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The addition reactions of organometallic reagents to monoprotected quinone bis-epoxides 7 and quinone monoacetals 5 provide a route to the highly oxygenated cyclohexanols 2 and 3; the application of this methodology to the preparation of the aranorosin analogue 4 is described.

Original language	English
Pages (from-to)	1589-1591
Number of pages	3
Journal	JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
Issue number	21
Publication status	Published - 1 Nov 1992

Keywords

PSEUDOARACHNIOTUS-ROSEUS

Cite this

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title = "ORGANOMETALLIC ADDITIONS TO PROTECTED QUINONE BIS-EPOXIDES AND QUINONE MONOACETALS - SYNTHESIS OF THE ARANOROSIN NUCLEUS",

abstract = "The addition reactions of organometallic reagents to monoprotected quinone bis-epoxides 7 and quinone monoacetals 5 provide a route to the highly oxygenated cyclohexanols 2 and 3; the application of this methodology to the preparation of the aranorosin analogue 4 is described.",

keywords = "PSEUDOARACHNIOTUS-ROSEUS",

author = "A MCKILLOP and TAYLOR, {R J K} and WATSON, {R J} and N LEWIS",

year = "1992",

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language = "English",

pages = "1589--1591",

journal = "JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS",

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AU - TAYLOR, R J K

AU - WATSON, R J

AU - LEWIS, N

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N2 - The addition reactions of organometallic reagents to monoprotected quinone bis-epoxides 7 and quinone monoacetals 5 provide a route to the highly oxygenated cyclohexanols 2 and 3; the application of this methodology to the preparation of the aranorosin analogue 4 is described.

AB - The addition reactions of organometallic reagents to monoprotected quinone bis-epoxides 7 and quinone monoacetals 5 provide a route to the highly oxygenated cyclohexanols 2 and 3; the application of this methodology to the preparation of the aranorosin analogue 4 is described.

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M3 - Article

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JO - JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS

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