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Oxidative addition of ether O-methyl bonds at a Pt(0) centre

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JournalChemical communications
DateE-pub ahead of print - 6 Feb 2014
DatePublished (current) - 2014
Volume50
Number of pages4
Pages (from-to)3914-3917
Early online date6/02/14
Original languageEnglish

Abstract

Pt(PCyp) (Cyp = cyclopentyl) undergoes C-O oxidative addition with 2,3,5,6-tetrafluoro-4-methoxypyridine, pentafluoroanisole, 2,3,5,6-tetrafluoroanisole and 2,3,6-trifluoroanisole yielding platinum methyl derivatives. The reactions occur in preference to C-H or C-F activation.

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