Abstract
The study of reactions by NMR spectroscopy is normally limited by the poor detection limits offered by the method. An overview is presented of how chemical reactions can be studied using parahydrogen-assisted NMR spectroscopy, where detected signals can have strengths that exceed those normally available by factors that approach 31,000. (C) 2008 Elsevier B.V. All rights reserved.
Original language | English |
---|---|
Pages (from-to) | 2278-2291 |
Number of pages | 14 |
Journal | COORDINATION CHEMISTRY REVIEWS |
Volume | 252 |
Issue number | 21-22 |
DOIs | |
Publication status | Published - Nov 2008 |
Keywords
- NMR
- Parahydrogen
- Mechanism
- Photochemistry
- Hydrogenation
- Catalysis
- HYDROGEN-INDUCED POLARIZATION
- NUCLEAR-MAGNETIC-RESONANCE
- DETECT SPECIES PRESENT
- RUTHENIUM DIHYDRIDE COMPLEXES
- OXIDATIVE ADDITION-REACTIONS
- IN-SITU
- HOMOGENEOUS HYDROGENATION
- SPIN POLARIZATION
- H-2 ADDITION
- RHODIUM(I)-CATALYZED HYDROGENATION