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Parahydrogen-based NMR methods as a mechanistic probe in inorganic chemistry

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JournalCOORDINATION CHEMISTRY REVIEWS
DatePublished - Nov 2008
Issue number21-22
Volume252
Number of pages14
Pages (from-to)2278-2291
Original languageEnglish

Abstract

The study of reactions by NMR spectroscopy is normally limited by the poor detection limits offered by the method. An overview is presented of how chemical reactions can be studied using parahydrogen-assisted NMR spectroscopy, where detected signals can have strengths that exceed those normally available by factors that approach 31,000. (C) 2008 Elsevier B.V. All rights reserved.

    Research areas

  • NMR, Parahydrogen, Mechanism, Photochemistry, Hydrogenation, Catalysis, HYDROGEN-INDUCED POLARIZATION, NUCLEAR-MAGNETIC-RESONANCE, DETECT SPECIES PRESENT, RUTHENIUM DIHYDRIDE COMPLEXES, OXIDATIVE ADDITION-REACTIONS, IN-SITU, HOMOGENEOUS HYDROGENATION, SPIN POLARIZATION, H-2 ADDITION, RHODIUM(I)-CATALYZED HYDROGENATION

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