Pd-Catalysed carbonylative Suzuki-Miyaura cross-couplings using Fe(CO)5under mild conditions: generation of a highly active, recyclable and scalable ‘Pd-Fe’ nanocatalyst

Zhuangli Zhu; Zhenhua Wang; Yajun Jian; Huaming Sun; Guofang Zhang; Jason M. Lynam; C. Robert McElroy; Thomas J. Burden; Rebecca L. Inight; Ian J.S. Fairlamb; Weiqiang Zhang; Ziwei Gao

doi:10.1039/d0gc03036h

Pd-Catalysed carbonylative Suzuki-Miyaura cross-couplings using Fe(CO)₅under mild conditions: generation of a highly active, recyclable and scalable ‘Pd-Fe’ nanocatalyst

Zhuangli Zhu, Zhenhua Wang, Yajun Jian, Huaming Sun, Guofang Zhang, Jason M. Lynam, C. Robert McElroy, Thomas J. Burden, Rebecca L. Inight, Ian J.S. Fairlamb^*, Weiqiang Zhang, Ziwei Gao

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The dual function and role of iron(0) pentacarbonyl [Fe(CO)₅] has been identified in gaseous CO-free carbonylative Suzuki-Miyaura cross-couplings, in which Fe(CO)₅supplied COin situ, leading to the propagation of catalytically active Pd-Fe nanoparticles. Compared with typical carbonylative reaction conditions, CO gas (at high pressures), specialised exogenous ligands and inert reaction conditions were avoided. Our developed reaction conditions are mild, do not require specialised CO high pressure equipment, and exhibit wide functional group tolerance, giving a library of biaryl ketones in good yields.

Original language	English
Pages (from-to)	920-926
Number of pages	7
Journal	Green Chemistry
Volume	23
Issue number	2
DOIs	https://doi.org/10.1039/d0gc03036h
Publication status	Published - 21 Jan 2021

Bibliographical note

Funding Information:
This work was supported by the grant from the National Natural Science Foundation of China (21371112 and 21446014), the 111 Project (B14041), the Fundamental Funds Research for the Central Universities (No. GK201501005, GK201503029, and 2016CSY002), the grant from the Fundamental Doctoral Fund of Ministry of Education of China (20120202120005), and the Program for Changjiang Scholars and Innovative Research Team in University (IRT_14R33). I. J. S. F. is grateful to the Royal Society for University Research Fellowship (2004-12). We thank Syngenta and the University of York for the iCASE funding and studentship to T. J. B. We also acknowledge the Leverhulme Trust for funding, enabling us to initiate this research (W. Z., I. J. S. F., and J. M. L.).

Publisher Copyright:
© The Royal Society of Chemistry 2021.

Copyright:
Copyright 2021 Elsevier B.V., All rights reserved.

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Pd-Catalysed carbonylative Suzuki–Miyaura crosscouplings using Fe(CO)5 under mild conditions: generation of a highly active, recyclable and scalable ‘Pd–Fe’ nanocatalystFinal published version, 1.61 MBLicence: CC BY-NC

Cite this

Zhu, Z., Wang, Z., Jian, Y., Sun, H., Zhang, G., Lynam, J. M., McElroy, C. R., Burden, T. J., Inight, R. L., Fairlamb, I. J. S., Zhang, W., & Gao, Z. (2021). Pd-Catalysed carbonylative Suzuki-Miyaura cross-couplings using Fe(CO)₅under mild conditions: generation of a highly active, recyclable and scalable ‘Pd-Fe’ nanocatalyst. Green Chemistry, 23(2), 920-926. https://doi.org/10.1039/d0gc03036h

@article{a3b209fe01724c5b84f227f5c25ca388,

title = "Pd-Catalysed carbonylative Suzuki-Miyaura cross-couplings using Fe(CO)5under mild conditions: generation of a highly active, recyclable and scalable {\textquoteleft}Pd-Fe{\textquoteright} nanocatalyst",

abstract = "The dual function and role of iron(0) pentacarbonyl [Fe(CO)5] has been identified in gaseous CO-free carbonylative Suzuki-Miyaura cross-couplings, in which Fe(CO)5supplied COin situ, leading to the propagation of catalytically active Pd-Fe nanoparticles. Compared with typical carbonylative reaction conditions, CO gas (at high pressures), specialised exogenous ligands and inert reaction conditions were avoided. Our developed reaction conditions are mild, do not require specialised CO high pressure equipment, and exhibit wide functional group tolerance, giving a library of biaryl ketones in good yields.",

author = "Zhuangli Zhu and Zhenhua Wang and Yajun Jian and Huaming Sun and Guofang Zhang and Lynam, {Jason M.} and McElroy, {C. Robert} and Burden, {Thomas J.} and Inight, {Rebecca L.} and Fairlamb, {Ian J.S.} and Weiqiang Zhang and Ziwei Gao",

note = "Funding Information: This work was supported by the grant from the National Natural Science Foundation of China (21371112 and 21446014), the 111 Project (B14041), the Fundamental Funds Research for the Central Universities (No. GK201501005, GK201503029, and 2016CSY002), the grant from the Fundamental Doctoral Fund of Ministry of Education of China (20120202120005), and the Program for Changjiang Scholars and Innovative Research Team in University (IRT_14R33). I. J. S. F. is grateful to the Royal Society for University Research Fellowship (2004-12). We thank Syngenta and the University of York for the iCASE funding and studentship to T. J. B. We also acknowledge the Leverhulme Trust for funding, enabling us to initiate this research (W. Z., I. J. S. F., and J. M. L.). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2021",

month = jan,

day = "21",

doi = "10.1039/d0gc03036h",

language = "English",

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Zhu, Z, Wang, Z, Jian, Y, Sun, H, Zhang, G, Lynam, JM , McElroy, CR, Burden, TJ, Inight, RL, Fairlamb, IJS, Zhang, W & Gao, Z 2021, 'Pd-Catalysed carbonylative Suzuki-Miyaura cross-couplings using Fe(CO)₅under mild conditions: generation of a highly active, recyclable and scalable ‘Pd-Fe’ nanocatalyst', Green Chemistry, vol. 23, no. 2, pp. 920-926. https://doi.org/10.1039/d0gc03036h

TY - JOUR

T1 - Pd-Catalysed carbonylative Suzuki-Miyaura cross-couplings using Fe(CO)5under mild conditions

T2 - generation of a highly active, recyclable and scalable ‘Pd-Fe’ nanocatalyst

AU - Zhu, Zhuangli

AU - Wang, Zhenhua

AU - Jian, Yajun

AU - Sun, Huaming

AU - Zhang, Guofang

AU - Lynam, Jason M.

AU - McElroy, C. Robert

AU - Burden, Thomas J.

AU - Inight, Rebecca L.

AU - Fairlamb, Ian J.S.

AU - Zhang, Weiqiang

AU - Gao, Ziwei

N1 - Funding Information: This work was supported by the grant from the National Natural Science Foundation of China (21371112 and 21446014), the 111 Project (B14041), the Fundamental Funds Research for the Central Universities (No. GK201501005, GK201503029, and 2016CSY002), the grant from the Fundamental Doctoral Fund of Ministry of Education of China (20120202120005), and the Program for Changjiang Scholars and Innovative Research Team in University (IRT_14R33). I. J. S. F. is grateful to the Royal Society for University Research Fellowship (2004-12). We thank Syngenta and the University of York for the iCASE funding and studentship to T. J. B. We also acknowledge the Leverhulme Trust for funding, enabling us to initiate this research (W. Z., I. J. S. F., and J. M. L.). Publisher Copyright: © The Royal Society of Chemistry 2021. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/1/21

Y1 - 2021/1/21

N2 - The dual function and role of iron(0) pentacarbonyl [Fe(CO)5] has been identified in gaseous CO-free carbonylative Suzuki-Miyaura cross-couplings, in which Fe(CO)5supplied COin situ, leading to the propagation of catalytically active Pd-Fe nanoparticles. Compared with typical carbonylative reaction conditions, CO gas (at high pressures), specialised exogenous ligands and inert reaction conditions were avoided. Our developed reaction conditions are mild, do not require specialised CO high pressure equipment, and exhibit wide functional group tolerance, giving a library of biaryl ketones in good yields.

AB - The dual function and role of iron(0) pentacarbonyl [Fe(CO)5] has been identified in gaseous CO-free carbonylative Suzuki-Miyaura cross-couplings, in which Fe(CO)5supplied COin situ, leading to the propagation of catalytically active Pd-Fe nanoparticles. Compared with typical carbonylative reaction conditions, CO gas (at high pressures), specialised exogenous ligands and inert reaction conditions were avoided. Our developed reaction conditions are mild, do not require specialised CO high pressure equipment, and exhibit wide functional group tolerance, giving a library of biaryl ketones in good yields.

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U2 - 10.1039/d0gc03036h

DO - 10.1039/d0gc03036h

M3 - Article

AN - SCOPUS:85100414319

SN - 1463-9270

VL - 23

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EP - 926

JO - Green Chemistry

JF - Green Chemistry

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