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Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis

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JournalACS Catalysis
DateAccepted/In press - 4 Jun 2020
DateE-pub ahead of print - 5 Jun 2020
DatePublished (current) - 2 Jul 2020
Issue number13
Volume10
Number of pages12
Pages (from-to)7250-7261
Early online date5/06/20
Original languageEnglish

Abstract

Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method for the generation of diverse and valuable radicals, typically via deoxygenation or desulfurization processes. This Perspective is a comprehensive evaluation of all studies using phosphoranyl radicals as tunable mediators in photoredox catalysis, highlighting how two distinct methods for phosphoranyl radical formation (radical addition and nucleophilic addition) can be used to generate versatile radical intermediates with diverse reactivity profiles.

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© 2020 American Chemical Society

    Research areas

  • phosphine, phosphoranyl, photoredox, radical, visible light

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