Polymer imprinting with iron-oxo-hydroxo clusters:  [Fe6O2(OH)2(O2CC(Cl)=CH2)12(H2O)2], [Fe6O2(OH)2(O2C-Ph-(CH)=CH2)12(H2O)2] and [{Fe(O2CC(Cl)=CH2)(OMe)2}10]

Paul Howard Walton; Adrian C. Whitwood; Aine T. Ryan; Spencer Harben; Frederick Mosselmans

doi:10.1039/c1dt11614b

Polymer imprinting with iron-oxo-hydroxo clusters: [Fe6O2(OH)2(O2CC(Cl)=CH2)12(H2O)2], [Fe6O2(OH)2(O2C-Ph-(CH)=CH2)12(H2O)2] and [{Fe(O2CC(Cl)=CH2)(OMe)2}10]

Paul Howard Walton, Adrian C. Whitwood, Aine T. Ryan, Spencer Harben, Frederick Mosselmans

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We report the syntheses of imprinted polymers using iron-oxo-hydroxo clusters as templates. Three new iron clusters, [Fe6O2(OH)2(O2CC(Cl)=CH2)12(H2O)2] (1), [{Fe(O2CC(Cl)=CH2)(OMe)2}10] (2) and [Fe6O2(OH)2(O2C–Ph–(CH)=CH2)12(H2O)2] (3) have been prepared from commercially-available carboxylic acids. Cluster-imprinted-polymers (CIPs) of 1, 2 and 3 were prepared with ethylene glycol dimethacrylate monomer, and of 1 with methyl methacrylate monomer. The imprinted sites within the CIPs were examined using EXAFS and Diffuse Reflectance UV/vis spectroscopy, demonstrating that the clusters 1, 2 and 3 were incorporated intact within the polymers. Extraction of the clusters from the CIPs imprinted with 1 and 3 gave new polymers that showed evidence of an imprinting effect.

Original language	English
Pages (from-to)	208-218
Journal	Dalton Transactions
Volume	41
Issue number	1
DOIs	https://doi.org/10.1039/c1dt11614b
Publication status	Published - 7 Jan 2012

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http://pubs.rsc.org/en/Content/ArticleLanding/2012/DT/c1dt11614b

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title = "Polymer imprinting with iron-oxo-hydroxo clusters: [Fe6O2(OH)2(O2CC(Cl)=CH2)12(H2O)2], [Fe6O2(OH)2(O2C-Ph-(CH)=CH2)12(H2O)2] and [{Fe(O2CC(Cl)=CH2)(OMe)2}10]",

abstract = "We report the syntheses of imprinted polymers using iron-oxo-hydroxo clusters as templates. Three new iron clusters, [Fe6O2(OH)2(O2CC(Cl)=CH2)12(H2O)2] (1), [{Fe(O2CC(Cl)=CH2)(OMe)2}10] (2) and [Fe6O2(OH)2(O2C–Ph–(CH)=CH2)12(H2O)2] (3) have been prepared from commercially-available carboxylic acids. Cluster-imprinted-polymers (CIPs) of 1, 2 and 3 were prepared with ethylene glycol dimethacrylate monomer, and of 1 with methyl methacrylate monomer. The imprinted sites within the CIPs were examined using EXAFS and Diffuse Reflectance UV/vis spectroscopy, demonstrating that the clusters 1, 2 and 3 were incorporated intact within the polymers. Extraction of the clusters from the CIPs imprinted with 1 and 3 gave new polymers that showed evidence of an imprinting effect.",

author = "Walton, {Paul Howard} and Whitwood, {Adrian C.} and Ryan, {Aine T.} and Spencer Harben and Frederick Mosselmans",

year = "2012",

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doi = "10.1039/c1dt11614b",

language = "English",

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T1 - Polymer imprinting with iron-oxo-hydroxo clusters

T2 - [Fe6O2(OH)2(O2CC(Cl)=CH2)12(H2O)2], [Fe6O2(OH)2(O2C-Ph-(CH)=CH2)12(H2O)2] and [{Fe(O2CC(Cl)=CH2)(OMe)2}10]

AU - Walton, Paul Howard

AU - Whitwood, Adrian C.

AU - Ryan, Aine T.

AU - Harben, Spencer

AU - Mosselmans, Frederick

PY - 2012/1/7

Y1 - 2012/1/7

N2 - We report the syntheses of imprinted polymers using iron-oxo-hydroxo clusters as templates. Three new iron clusters, [Fe6O2(OH)2(O2CC(Cl)=CH2)12(H2O)2] (1), [{Fe(O2CC(Cl)=CH2)(OMe)2}10] (2) and [Fe6O2(OH)2(O2C–Ph–(CH)=CH2)12(H2O)2] (3) have been prepared from commercially-available carboxylic acids. Cluster-imprinted-polymers (CIPs) of 1, 2 and 3 were prepared with ethylene glycol dimethacrylate monomer, and of 1 with methyl methacrylate monomer. The imprinted sites within the CIPs were examined using EXAFS and Diffuse Reflectance UV/vis spectroscopy, demonstrating that the clusters 1, 2 and 3 were incorporated intact within the polymers. Extraction of the clusters from the CIPs imprinted with 1 and 3 gave new polymers that showed evidence of an imprinting effect.

AB - We report the syntheses of imprinted polymers using iron-oxo-hydroxo clusters as templates. Three new iron clusters, [Fe6O2(OH)2(O2CC(Cl)=CH2)12(H2O)2] (1), [{Fe(O2CC(Cl)=CH2)(OMe)2}10] (2) and [Fe6O2(OH)2(O2C–Ph–(CH)=CH2)12(H2O)2] (3) have been prepared from commercially-available carboxylic acids. Cluster-imprinted-polymers (CIPs) of 1, 2 and 3 were prepared with ethylene glycol dimethacrylate monomer, and of 1 with methyl methacrylate monomer. The imprinted sites within the CIPs were examined using EXAFS and Diffuse Reflectance UV/vis spectroscopy, demonstrating that the clusters 1, 2 and 3 were incorporated intact within the polymers. Extraction of the clusters from the CIPs imprinted with 1 and 3 gave new polymers that showed evidence of an imprinting effect.

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U2 - 10.1039/c1dt11614b

DO - 10.1039/c1dt11614b

M3 - Article

SN - 1477-9234

VL - 41

SP - 208

EP - 218

JO - Dalton Transactions

JF - Dalton Transactions

IS - 1

ER -

Polymer imprinting with iron-oxo-hydroxo clusters: [Fe6O2(OH)2(O2CC(Cl)=CH2)12(H2O)2], [Fe6O2(OH)2(O2C-Ph-(CH)=CH2)12(H2O)2] and [{Fe(O2CC(Cl)=CH2)(OMe)2}10]

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