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Pot, atom and step economic (PASE) synthesis of highly functionalized piperidines: a five-component condensation

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JournalTetrahedron Letters
DatePublished - 23 Jul 2007
Issue number30
Volume48
Number of pages4
Pages (from-to)5209-5212
Original languageEnglish

Abstract

The diastereoselective pot, atom and step economic (PASE) synthesis of highly functionalized piperidines has been realized. The procedure simply involves mixing methyl acetoacetate, 2 equiv of aldehyde and 2 equiv of aniline together in the presence of InCl3. In most cases the piperidine precipitates out of solution. (c) 2007 Elsevier Ltd. All rights reserved.

    Research areas

  • piperidines, PASE, one-pot, multi-component, MAITLAND-JAPP REACTION, IDEAL SYNTHESIS, TETRAHYDROPYRAN-4-ONES, CONSTRUCTION, AMINES, WATER

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