Preparation of cationic cobalt phenoxide and ethoxide complexes and their reversible reaction with carbon dioxide

S J Archibald, S P Foxon, J D Freeman, J E Hobson, R N Perutz, P H Walton

Research output: Contribution to journalArticlepeer-review

Abstract

The complexes [Co(TCT)(OR)]BPh4 (R = Et, Ph; TCT = cis, cis-1,3,5- tris(cinnamylideneamino) cyclohexane) have been prepared and characterised by X-ray diffraction; in coordinating solvents both complexes react reversibly with carbon dioxide to form organocarbonate complexes.

Original languageEnglish
Pages (from-to)2797-2799
Number of pages3
JournalJOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue number14
DOIs
Publication statusPublished - 2002

Keywords

  • STRUCTURAL CHARACTERIZATION
  • INSERTION REACTIONS
  • COPOLYMERIZATION
  • EPOXIDES
  • BOND

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