Primary amido substituted diborane(4) compounds and imidodiborate(4) anions

R A  Baber; J P H  Charmant; A J R  Cook; N E  Farthing; M F  Haddow; N C  Norman; A G  Orpen; C A  Russell; J M  Slattery

doi:10.1039/b509653g

Primary amido substituted diborane(4) compounds and imidodiborate(4) anions

R A Baber, J P H Charmant, A J R Cook, N E Farthing, M F Haddow, N C Norman, A G Orpen, C A Russell, J M Slattery

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Treatment of the diborane(4) compound B-2(NMe2)(4) with aniline or 2,6-dimethylaniline results in the primary amido compounds B-2(NHR)(4) ( R = Ph, 2,6-Me2C6H3); subsequent treatment with n-BuLi in toluene in each case affords the first examples of anionic imidodiborates namely Li-4(thf)(6)B-2(NPh)(4) and Li-4(thf)(4)B-2(N-2,6-Me2C6H3)(4); all complexes have been characterised crystallographically.

Original language	English
Pages (from-to)	3137-3139
Number of pages	3
Journal	Dalton Transactions
Issue number	19
DOIs	https://doi.org/10.1039/b509653g
Publication status	Published - 2005

Keywords

IMIDO ANALOGS
CHEMISTRY
BORON

Access to Document

10.1039/b509653g

Cite this

@article{9f26032786df4376bacc5d589fe2aeb7,

title = "Primary amido substituted diborane(4) compounds and imidodiborate(4) anions",

abstract = "Treatment of the diborane(4) compound B-2(NMe2)(4) with aniline or 2,6-dimethylaniline results in the primary amido compounds B-2(NHR)(4) ( R = Ph, 2,6-Me2C6H3); subsequent treatment with n-BuLi in toluene in each case affords the first examples of anionic imidodiborates namely Li-4(thf)(6)B-2(NPh)(4) and Li-4(thf)(4)B-2(N-2,6-Me2C6H3)(4); all complexes have been characterised crystallographically.",

keywords = "IMIDO ANALOGS, CHEMISTRY, BORON",

author = "Baber, {R A} and Charmant, {J P H} and Cook, {A J R} and Farthing, {N E} and Haddow, {M F} and Norman, {N C} and Orpen, {A G} and Russell, {C A} and Slattery, {J M}",

year = "2005",

doi = "10.1039/b509653g",

language = "English",

pages = "3137--3139",

journal = "Dalton Transactions",

issn = "1477-9234",

publisher = "The Royal Society of Chemistry",

number = "19",

}

TY - JOUR

T1 - Primary amido substituted diborane(4) compounds and imidodiborate(4) anions

AU - Baber, R A

AU - Charmant, J P H

AU - Cook, A J R

AU - Farthing, N E

AU - Haddow, M F

AU - Norman, N C

AU - Orpen, A G

AU - Russell, C A

AU - Slattery, J M

PY - 2005

Y1 - 2005

N2 - Treatment of the diborane(4) compound B-2(NMe2)(4) with aniline or 2,6-dimethylaniline results in the primary amido compounds B-2(NHR)(4) ( R = Ph, 2,6-Me2C6H3); subsequent treatment with n-BuLi in toluene in each case affords the first examples of anionic imidodiborates namely Li-4(thf)(6)B-2(NPh)(4) and Li-4(thf)(4)B-2(N-2,6-Me2C6H3)(4); all complexes have been characterised crystallographically.

AB - Treatment of the diborane(4) compound B-2(NMe2)(4) with aniline or 2,6-dimethylaniline results in the primary amido compounds B-2(NHR)(4) ( R = Ph, 2,6-Me2C6H3); subsequent treatment with n-BuLi in toluene in each case affords the first examples of anionic imidodiborates namely Li-4(thf)(6)B-2(NPh)(4) and Li-4(thf)(4)B-2(N-2,6-Me2C6H3)(4); all complexes have been characterised crystallographically.

KW - IMIDO ANALOGS

KW - CHEMISTRY

KW - BORON

U2 - 10.1039/b509653g

DO - 10.1039/b509653g

M3 - Article

SN - 1477-9234

SP - 3137

EP - 3139

JO - Dalton Transactions

JF - Dalton Transactions

IS - 19

ER -