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Radical addition reactions of chiral phosphorus hydrides

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JournalTETRAHEDRON-ASYMMETRY
DatePublished - 3 Oct 2003
Issue number19
Volume14
Number of pages3
Pages (from-to)2849-2851
Original languageEnglish

Abstract

Intermolecular radical addition of a (1R,2R,3S,5R)-(-)-pinanediol-derived thiophosphite leads to the diastereoselective formation of organophosphorus adducts. Addition of the intermediate phosphonothioyl radical to electron-rich alkenes or alkynes occurs with retention of configuration at phosphorus. (C) 2003 Elsevier Ltd. All rights reserved.

    Research areas

  • ASYMMETRIC-SYNTHESIS, EFFICIENT SYNTHESIS, BORONIC ESTERS, PHOSPHONOTHIOATES, PHOSPHONATES, ALKENES

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