RAPID CHARACTERIZATION OF RHODIUM DIHYDRIDES BY NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY USING INDIRECT 2-DIMENSIONAL METHODS AND PARA-HYDROGEN

S B  DUCKETT; G K  BARLOW; M G  PARTRIDGE; B A  MESSERLE

RAPID CHARACTERIZATION OF RHODIUM DIHYDRIDES BY NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY USING INDIRECT 2-DIMENSIONAL METHODS AND PARA-HYDROGEN

S B DUCKETT, G K BARLOW, M G PARTRIDGE, B A MESSERLE

Chemistry

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

When [RhH2(PMe(3))(3)Cl], incorporating chemically inequivalent hydrides, and [RhH2(PMe(3))(4)]Cl, containing magnetically inequivalent hydrides.,were generated using para-enriched hydrogen, their H-1-Rh-103 and H-1-P-31 two-dimensional NMR spectra were quickly obtained from < 1 mg of complex with and without the aid of pulsed field gradients.

Original language	English
Pages (from-to)	3427-3429
Number of pages	3
Journal	JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue number	20
Publication status	Published - 21 Oct 1995

Keywords

PHOSPHINE COMPLEXES
PARAHYDROGEN
POLARIZATION
ACTIVATION
SPIN

Cite this

@article{e8f3a16ee9a54182b5660462c942c418,

title = "RAPID CHARACTERIZATION OF RHODIUM DIHYDRIDES BY NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY USING INDIRECT 2-DIMENSIONAL METHODS AND PARA-HYDROGEN",

abstract = "When [RhH2(PMe(3))(3)Cl], incorporating chemically inequivalent hydrides, and [RhH2(PMe(3))(4)]Cl, containing magnetically inequivalent hydrides.,were generated using para-enriched hydrogen, their H-1-Rh-103 and H-1-P-31 two-dimensional NMR spectra were quickly obtained from < 1 mg of complex with and without the aid of pulsed field gradients.",

keywords = "PHOSPHINE COMPLEXES, PARAHYDROGEN, POLARIZATION, ACTIVATION, SPIN",

author = "DUCKETT, {S B} and BARLOW, {G K} and PARTRIDGE, {M G} and MESSERLE, {B A}",

year = "1995",

month = oct,

day = "21",

language = "English",

pages = "3427--3429",

journal = "JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS",

issn = "1472-7773",

publisher = "The Royal Society of Chemistry",

number = "20",

}

TY - JOUR

T1 - RAPID CHARACTERIZATION OF RHODIUM DIHYDRIDES BY NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY USING INDIRECT 2-DIMENSIONAL METHODS AND PARA-HYDROGEN

AU - DUCKETT, S B

AU - BARLOW, G K

AU - PARTRIDGE, M G

AU - MESSERLE, B A

PY - 1995/10/21

Y1 - 1995/10/21

N2 - When [RhH2(PMe(3))(3)Cl], incorporating chemically inequivalent hydrides, and [RhH2(PMe(3))(4)]Cl, containing magnetically inequivalent hydrides.,were generated using para-enriched hydrogen, their H-1-Rh-103 and H-1-P-31 two-dimensional NMR spectra were quickly obtained from < 1 mg of complex with and without the aid of pulsed field gradients.

AB - When [RhH2(PMe(3))(3)Cl], incorporating chemically inequivalent hydrides, and [RhH2(PMe(3))(4)]Cl, containing magnetically inequivalent hydrides.,were generated using para-enriched hydrogen, their H-1-Rh-103 and H-1-P-31 two-dimensional NMR spectra were quickly obtained from < 1 mg of complex with and without the aid of pulsed field gradients.

KW - PHOSPHINE COMPLEXES

KW - PARAHYDROGEN

KW - POLARIZATION

KW - ACTIVATION

KW - SPIN

M3 - Comment/debate

SN - 1472-7773

SP - 3427

EP - 3429

JO - JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS

JF - JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS

IS - 20

ER -