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From the same journal

RAPID CHARACTERIZATION OF RHODIUM DIHYDRIDES BY NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY USING INDIRECT 2-DIMENSIONAL METHODS AND PARA-HYDROGEN

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Publication details

JournalJOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
DatePublished - 21 Oct 1995
Issue number20
Number of pages3
Pages (from-to)3427-3429
Original languageEnglish

Abstract

When [RhH2(PMe(3))(3)Cl], incorporating chemically inequivalent hydrides, and [RhH2(PMe(3))(4)]Cl, containing magnetically inequivalent hydrides.,were generated using para-enriched hydrogen, their H-1-Rh-103 and H-1-P-31 two-dimensional NMR spectra were quickly obtained from < 1 mg of complex with and without the aid of pulsed field gradients.

    Research areas

  • PHOSPHINE COMPLEXES, PARAHYDROGEN, POLARIZATION, ACTIVATION, SPIN

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