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Rapid Ring-Opening Metathesis Polymerization of Monomers Obtained from Biomass-Derived Furfuryl Amines and Maleic Anhydride

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JournalCHEMSUSCHEM
DateAccepted/In press - 5 Apr 2019
DateE-pub ahead of print - 17 May 2019
DatePublished (current) - 11 Jun 2019
Issue number11
Volume12
Number of pages9
Pages (from-to)2393-2401
Early online date17/05/19
Original languageEnglish

Abstract

Well-controlled and extremely rapid ring-opening metathesis polymerization of unusual oxanorbornene lactam esters by Grubbs third-generation catalyst is used to prepare a range of bio-based homo- and copolymers. Bio-derived oxanorbornene lactam monomers were prepared at room temperature from maleic anhydride and secondary furfuryl amines by using a 100 % atom economical, tandem Diels–Alder lactamization reaction, followed by esterification. Several of the resulting homo- and copolymers show good control over polymer molecular weight and have narrow molecular weight distributions.

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© 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

    Research areas

  • biomass, homogeneous catalysis, metathesis, polymerization, sustainable polymers

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