By the same authors

From the same journal

Reaction of tetramethylammonium fluoride with trifluoromethyltrimethylsilane

Research output: Contribution to journalArticle

Author(s)

  • D J Adams
  • J H Clark
  • L B Hansen
  • V C Sanders
  • S J Tavener

Department/unit(s)

Publication details

JournalJOURNAL OF FLUORINE CHEMISTRY
DatePublished - 2 Nov 1998
Issue number2
Volume92
Number of pages3
Pages (from-to)123-125
Original languageEnglish

Abstract

Tetramethylammonium fluoride reacts with either triluoromethyltrimethylsilane or trimethylsilylacetonitrile in acetonitrile to form a pentacoordinate silicon species, which can act as a source of either fluoride or cyanomethyl carbanion, depending on substrate. (C) 1998 Elsevier Science S.A. All rights reserved.

    Research areas

  • Ruppert's reagent, trifluoromethane, TMAF, fluorodenitration

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