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Recent developments in organocatalysed transformations of epoxides and carbon dioxide into cyclic carbonates

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Publication details

JournalGreen Chemistry
DateAccepted/In press - 3 Dec 2020
DatePublished (current) - 7 Jan 2021
Issue number1
Volume23
Number of pages42
Pages (from-to)77-118
Original languageEnglish

Abstract

This review is focused on the rapidly developing area of organocatalysed cyclic carbonate synthesis. It starts with an introduction to carbon capture and utilisation in general, which introduces the importance of cyclic carbonates. The various mechanisms for cyclic carbonate synthesis are next discussed with a focus on the relative and absolute stereochemical consequences of each mechanism and how this combined with other physical organic chemistry techniques can be used to distinguish between three main mechanistic classes: epoxide activation; carbon dioxide activation and dual activation. Section 2 of the review then discusses recently reported homogeneous organocatalysed systems whilst section 3 surveys recently reported heterogeneous catalyst systems. For each catalyst system, the mechanism of action is discussed with reference to the mechanisms introduced at the start of the review and key parameters such as the optimal temperature, pressure and catalyst loading are given combined with information on substrate scope and yields. This allows the various catalysts to be critically compared on the basis of whichever parameter(s) are of most significance to the reader. A Final Thoughts/Perspective section focusses on the limitations of the use of turnover frequency and turnover number to compare catalysts in this reaction and makes the case for authors to use of a wider range of green metrics when reporting new catalysts. Finally, the Conclusions section focuses on future challenges such as the use of biomass derived epoxides, use of impure carbon dioxide and the need to develop new and existing highly active catalysts out of the laboratory and into real world applications.

Bibliographical note

Funding Information:
The authors thank the Program for Public Technology of Zhejiang Province (No. LGF18B060003) and the State Scholarship Fund from the China Scholarship Council (No. 201908330607) for financial support.

Publisher Copyright:
© The Royal Society of Chemistry.

Copyright:
Copyright 2021 Elsevier B.V., All rights reserved.

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