REDUCTION OF CARBOXYLIC ESTERS AND ACIDS BY POLYMETHYLHYDROSILOXANE CATALYZED BY TITANIUM AND ZIRCONIUM ALKOXIDES

S W  BREEDEN; N J  LAWRENCE

REDUCTION OF CARBOXYLIC ESTERS AND ACIDS BY POLYMETHYLHYDROSILOXANE CATALYZED BY TITANIUM AND ZIRCONIUM ALKOXIDES

Chemistry

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

A range of carboxylic esters and acids has been converted efficiently to the corresponding alcohols with polymethylhydrosiloxane in the presence of titanium (IV) isopropoxide or zirconium (IV) ethoxide; a stereogenic centre adjacent to the ester is unaffected.

Original language	English
Pages (from-to)	833-835
Number of pages	3
Journal	Synlett
Issue number	10
Publication status	Published - Oct 1994

Keywords

REDUCTION
CARBOXYLIC ESTERS
POLYMETHYLHYDROSILOXANE
TITANIUM (IV) ISOPROPOXIDE
CARBONYL-COMPOUNDS

Cite this

@article{60f7324cd058405e8ef18e58dfa62df4,

title = "REDUCTION OF CARBOXYLIC ESTERS AND ACIDS BY POLYMETHYLHYDROSILOXANE CATALYZED BY TITANIUM AND ZIRCONIUM ALKOXIDES",

abstract = "A range of carboxylic esters and acids has been converted efficiently to the corresponding alcohols with polymethylhydrosiloxane in the presence of titanium (IV) isopropoxide or zirconium (IV) ethoxide; a stereogenic centre adjacent to the ester is unaffected.",

keywords = "REDUCTION, CARBOXYLIC ESTERS, POLYMETHYLHYDROSILOXANE, TITANIUM (IV) ISOPROPOXIDE, CARBONYL-COMPOUNDS",

author = "BREEDEN, {S W} and LAWRENCE, {N J}",

year = "1994",

month = oct,

language = "English",

pages = "833--835",

journal = "Synlett",

issn = "1437-2096",

publisher = "Georg Thieme Verlag",

number = "10",

}

TY - JOUR

T1 - REDUCTION OF CARBOXYLIC ESTERS AND ACIDS BY POLYMETHYLHYDROSILOXANE CATALYZED BY TITANIUM AND ZIRCONIUM ALKOXIDES

AU - BREEDEN, S W

AU - LAWRENCE, N J

PY - 1994/10

Y1 - 1994/10

N2 - A range of carboxylic esters and acids has been converted efficiently to the corresponding alcohols with polymethylhydrosiloxane in the presence of titanium (IV) isopropoxide or zirconium (IV) ethoxide; a stereogenic centre adjacent to the ester is unaffected.

AB - A range of carboxylic esters and acids has been converted efficiently to the corresponding alcohols with polymethylhydrosiloxane in the presence of titanium (IV) isopropoxide or zirconium (IV) ethoxide; a stereogenic centre adjacent to the ester is unaffected.

KW - REDUCTION

KW - CARBOXYLIC ESTERS

KW - POLYMETHYLHYDROSILOXANE

KW - TITANIUM (IV) ISOPROPOXIDE

KW - CARBONYL-COMPOUNDS

M3 - Comment/debate

SN - 1437-2096

SP - 833

EP - 835

JO - Synlett

JF - Synlett

IS - 10

ER -