Refocused linewidths less than 10 Hz in 1H solid-state NMR

Federico M. Paruzzo; Gabriele Stevanato; Meghan Eileen Halse; Judith Schlagnitweit; Daniele Mammoli; Anne Lesage; Lyndon Emsley

doi:10.1016/j.jmr.2018.06.001

Refocused linewidths less than 10 Hz in 1H solid-state NMR

Federico M. Paruzzo, Gabriele Stevanato, Meghan Eileen Halse, Judith Schlagnitweit, Daniele Mammoli, Anne Lesage, Lyndon Emsley

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Coherence lifetimes in homonuclear dipolar decoupled 1
H solid-state NMR experiments are usually on
the order of a few ms. We discover an oscillation that limits the lifetime of the coherences by recording
spin-echo dephasing curves. We find that this oscillation can be removed by the application of a double
spin-echo experiment, leading to coherence lifetimes of more than 45 ms in adamantane and more that
22 ms in b-AspAla, corresponding to refocused linewidths of less than 7 and 14 Hz respectively.

Original language	English
Pages (from-to)	41-46
Journal	Journal of Magnetic Resonance
Volume	293
Early online date	2 Jun 2018
DOIs	https://doi.org/10.1016/j.jmr.2018.06.001
Publication status	E-pub ahead of print - 2 Jun 2018

Bibliographical note

Access to Document

10.1016/j.jmr.2018.06.001

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Cite this

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title = "Refocused linewidths less than 10 Hz in 1H solid-state NMR",

abstract = "Coherence lifetimes in homonuclear dipolar decoupled 1H solid-state NMR experiments are usually onthe order of a few ms. We discover an oscillation that limits the lifetime of the coherences by recordingspin-echo dephasing curves. We find that this oscillation can be removed by the application of a doublespin-echo experiment, leading to coherence lifetimes of more than 45 ms in adamantane and more that22 ms in b-AspAla, corresponding to refocused linewidths of less than 7 and 14 Hz respectively.",

author = "Paruzzo, {Federico M.} and Gabriele Stevanato and Halse, {Meghan Eileen} and Judith Schlagnitweit and Daniele Mammoli and Anne Lesage and Lyndon Emsley",

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AU - Paruzzo, Federico M.

AU - Stevanato, Gabriele

AU - Halse, Meghan Eileen

AU - Schlagnitweit, Judith

AU - Mammoli, Daniele

AU - Lesage, Anne

AU - Emsley, Lyndon

PY - 2018/6/2

Y1 - 2018/6/2

N2 - Coherence lifetimes in homonuclear dipolar decoupled 1H solid-state NMR experiments are usually onthe order of a few ms. We discover an oscillation that limits the lifetime of the coherences by recordingspin-echo dephasing curves. We find that this oscillation can be removed by the application of a doublespin-echo experiment, leading to coherence lifetimes of more than 45 ms in adamantane and more that22 ms in b-AspAla, corresponding to refocused linewidths of less than 7 and 14 Hz respectively.

AB - Coherence lifetimes in homonuclear dipolar decoupled 1H solid-state NMR experiments are usually onthe order of a few ms. We discover an oscillation that limits the lifetime of the coherences by recordingspin-echo dephasing curves. We find that this oscillation can be removed by the application of a doublespin-echo experiment, leading to coherence lifetimes of more than 45 ms in adamantane and more that22 ms in b-AspAla, corresponding to refocused linewidths of less than 7 and 14 Hz respectively.

U2 - 10.1016/j.jmr.2018.06.001

DO - 10.1016/j.jmr.2018.06.001

M3 - Article

SN - 1090-7807

VL - 293

SP - 41

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JO - Journal of Magnetic Resonance

JF - Journal of Magnetic Resonance

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