Regioselective alkylation of a methylene group via meta-bridging of calix[4]arenes

Petr Slavík; Hana Dvořáková; Václav Eigner; Pavel Lhoták

doi:10.1039/c4cc04356a

Regioselective alkylation of a methylene group via meta-bridging of calix[4]arenes

Petr Slavík, Hana Dvořáková, Václav Eigner, Pavel Lhoták^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The meta-iodo derivative, fixed in the cone conformation, enables the gram-scale preparation of a meta-bridged calix[4]arene. This intermediate, possessing a fluorene moiety within the macrocyclic skeleton, can be regioselectively alkylated on the corresponding methylene bridge to form a unique substitution pattern in classical calixarene chemistry. This journal is

Original language	English
Pages (from-to)	10112-10114
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	70
DOIs	https://doi.org/10.1039/c4cc04356a
Publication status	Published - 11 Sept 2014

Access to Document

10.1039/c4cc04356a

Cite this

@article{f157ae96e65c4574a9b64e8a72d3d0a2,

title = "Regioselective alkylation of a methylene group via meta-bridging of calix[4]arenes",

abstract = "The meta-iodo derivative, fixed in the cone conformation, enables the gram-scale preparation of a meta-bridged calix[4]arene. This intermediate, possessing a fluorene moiety within the macrocyclic skeleton, can be regioselectively alkylated on the corresponding methylene bridge to form a unique substitution pattern in classical calixarene chemistry. This journal is",

author = "Petr Slav{\'i}k and Hana Dvo{\v r}{\'a}kov{\'a} and V{\'a}clav Eigner and Pavel Lhot{\'a}k",

year = "2014",

month = sep,

day = "11",

doi = "10.1039/c4cc04356a",

language = "English",

volume = "50",

pages = "10112--10114",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "70",

}

TY - JOUR

T1 - Regioselective alkylation of a methylene group via meta-bridging of calix[4]arenes

AU - Slavík, Petr

AU - Dvořáková, Hana

AU - Eigner, Václav

AU - Lhoták, Pavel

PY - 2014/9/11

Y1 - 2014/9/11

N2 - The meta-iodo derivative, fixed in the cone conformation, enables the gram-scale preparation of a meta-bridged calix[4]arene. This intermediate, possessing a fluorene moiety within the macrocyclic skeleton, can be regioselectively alkylated on the corresponding methylene bridge to form a unique substitution pattern in classical calixarene chemistry. This journal is

AB - The meta-iodo derivative, fixed in the cone conformation, enables the gram-scale preparation of a meta-bridged calix[4]arene. This intermediate, possessing a fluorene moiety within the macrocyclic skeleton, can be regioselectively alkylated on the corresponding methylene bridge to form a unique substitution pattern in classical calixarene chemistry. This journal is

UR - http://www.scopus.com/inward/record.url?scp=84905568879&partnerID=8YFLogxK

U2 - 10.1039/c4cc04356a

DO - 10.1039/c4cc04356a

M3 - Article

AN - SCOPUS:84905568879

SN - 1359-7345

VL - 50

SP - 10112

EP - 10114

JO - Chemical Communications

JF - Chemical Communications

IS - 70

ER -

Regioselective alkylation of a methylene group via meta-bridging of calix[4]arenes

Abstract

Access to Document

Other files and links

Cite this