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Regioselective (site-selective) functionalisation of unsaturated halogenated nitrogen, oxygen and sulfur heterocycles by Pd-catalysed cross-couplings and direct arylation processes

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JournalChemical Society Reviews
DatePublished - 2007
Issue number7
Volume36
Number of pages10
Pages (from-to)1036-1045
Original languageEnglish

Abstract

This tutorial review focuses on several practical synthetic transformations utilising palladium catalysis that facilitate the synthesis of functionalised unsaturated heterocycles in a regioselective ( site-selective) manner. Cross-couplings of electron-deficient, electron-neutral and electron-rich unsaturated halogenated heterocycles with various organometallic reagents, and other types of nucleophiles, are detailed. Direct arylation of electron-rich unsaturated heterocyclic compounds by C - H functionalisation is also presented.

    Research areas

  • EFFICIENT SYNTHESIS, ORGANIC-SYNTHESIS, PYRIDINE HALIDES, ARYL CHLORIDES, BORONIC ACIDS, PALLADIUM, 3,5-DIBROMO-2-PYRONE, LIGAND, PYRIMIDINES, DERIVATIVES

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