Rhodium(II)-catalysed tandem aziridination and ring-opening: - Research Database, The University of York

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Rhodium(II)-catalysed tandem aziridination and ring-opening: Stereoselective synthesis of functionalised tetrahydrofurans

Research output: Contribution to journal › Article

Published copy (DOI)

10.1039/c4cc05159a

Author(s)

William P. Unsworth
Nicola Clark
Thomas O. Ronson
Kiri Stevens
Amber L. Thompson
Scott G. Lamont
Jeremy Robertson

Department/unit(s)

Publication details

Journal	Chemical Communications
Date	Published - 6 Aug 2014
Issue number	77
Volume	50
Number of pages	4
Pages (from-to)	11393-11396
Original language	English

Abstract

Aziridines formed upon treatment of allylic carbamates and homoallylic sulfamates with Rh(II) carboxylate catalysts under oxidative conditions are trapped by suitably-disposed hydroxyl groups to give functionalised tetrahydrofurans.

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