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Rhodium(II)-catalysed tandem aziridination and ring-opening: Stereoselective synthesis of functionalised tetrahydrofurans

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JournalChemical Communications
DatePublished - 6 Aug 2014
Issue number77
Volume50
Number of pages4
Pages (from-to)11393-11396
Original languageEnglish

Abstract

Aziridines formed upon treatment of allylic carbamates and homoallylic sulfamates with Rh(II) carboxylate catalysts under oxidative conditions are trapped by suitably-disposed hydroxyl groups to give functionalised tetrahydrofurans.

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