By the same authors

From the same journal

Ring-Opening Metathesis Polymerization of Tertiary Amide Monomers Derived from a Biobased Oxanorbornene

Research output: Contribution to journalArticle

Full text download(s)

Published copy (DOI)

Author(s)

Department/unit(s)

Publication details

JournalACS Sustainable Chemistry and Engineering
DateAccepted/In press - 11 Jun 2018
DateE-pub ahead of print - 11 Jun 2018
DatePublished (current) - 6 Aug 2018
Issue number8
Volume6
Number of pages9
Pages (from-to)9744-9752
Early online date11/06/18
Original languageEnglish

Abstract

Ring-opening metathesis polymerization (ROMP) of biobased oxanorbornene amides by Grubbs second generation catalyst was used to prepare a range of well-defined homo- and copolymers. A series of 11 amide monomers, featuring a variety of functionalities including amino acids and peptides, have been synthesized from a biobased oxanorbornene acid, prepared through the 100% atom economical tandem Diels-Alder lactonization between itaconic anhydride and furfuryl alcohol. The polymerization has been shown to be well-controlled, with the prepared homo- and copolymers possessing controlled molecular weights with narrow polydispersities.

Bibliographical note

© 2018 American Chemical Society. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

    Research areas

  • Diels-Alder, Furfuryl alcohol, Itaconic anhydride, Lactonization, Platform molecules, Ring-opening metathesis polymerization

Discover related content

Find related publications, people, projects, datasets and more using interactive charts.

View graph of relations