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Ring-Opening Metathesis Polymerization of Tertiary Amide Monomers Derived from a Biobased Oxanorbornene
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Publication details
| Journal | ACS Sustainable Chemistry and Engineering |
|---|---|
| Date | Accepted/In press - 11 Jun 2018 |
| Date | E-pub ahead of print - 11 Jun 2018 |
| Date | Published (current) - 6 Aug 2018 |
| Issue number | 8 |
| Volume | 6 |
| Number of pages | 9 |
| Pages (from-to) | 9744-9752 |
| Early online date | 11/06/18 |
| Original language | English |
Abstract
Ring-opening metathesis polymerization (ROMP) of biobased oxanorbornene amides by Grubbs second generation catalyst was used to prepare a range of well-defined homo- and copolymers. A series of 11 amide monomers, featuring a variety of functionalities including amino acids and peptides, have been synthesized from a biobased oxanorbornene acid, prepared through the 100% atom economical tandem Diels-Alder lactonization between itaconic anhydride and furfuryl alcohol. The polymerization has been shown to be well-controlled, with the prepared homo- and copolymers possessing controlled molecular weights with narrow polydispersities.
Bibliographical note
© 2018 American Chemical Society. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.
- Diels-Alder, Furfuryl alcohol, Itaconic anhydride, Lactonization, Platform molecules, Ring-opening metathesis polymerization
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