Selective preparation of the [3,5-tBu(2)-1,2,4-C2P3](-) ion and synthesis and structure of the cationic species nido-[3,5-tBu(2)-1,2,4-C2P3](+), isoelectronic with [C5R5](+)

J M  Lynam; M C  Copsey; M  Green; J C  Jeffery; J E  McGrady; C A  Russell; J M  Slattery; A C  Swain

doi:10.1002/anie.200351096

Selective preparation of the [3,5-tBu(2)-1,2,4-C2P3](-) ion and synthesis and structure of the cationic species nido-[3,5-tBu(2)-1,2,4-C2P3](+), isoelectronic with [C5R5](+)

J M Lynam, M C Copsey, M Green, J C Jeffery, J E McGrady, C A Russell, J M Slattery, A C Swain

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Building pyramids: The first P-C cluster, namely, the novel nido species 2, is readily prepared from 1 (=CtBu), which is also an excellent precursor for the selective synthesis of the anion 3. DFT calculations show that there is a switch in the global minimum, on the introduction of three P atoms (CH) into the [C5H5]+ ion, from cyclic-unsaturated to saturated cage species, such as 2.

Original language	English
Pages (from-to)	2778-2782
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	42
Issue number	24
DOIs	https://doi.org/10.1002/anie.200351096
Publication status	Published - 17 Jun 2003

Keywords

anions
cations
density functional calculations
phosphorus
phosphorus heterocycles
STABLE PENTAMETHYLCYCLOPENTADIENYL CATION
ORGANOPHOSPHORUS COMPOUNDS
CRYSTAL-STRUCTURE
VALENCE ISOMER
COMPOUND
C5H5+
BOND

Access to Document

10.1002/anie.200351096

http://dx.doi.org/10.1002/anie.200351096

Cite this

Lynam, J. M., Copsey, M. C., Green, M., Jeffery, J. C., McGrady, J. E., Russell, C. A., Slattery, J. M., & Swain, A. C. (2003). Selective preparation of the [3,5-tBu(2)-1,2,4-C2P3](-) ion and synthesis and structure of the cationic species nido-[3,5-tBu(2)-1,2,4-C2P3](+), isoelectronic with [C5R5](+). Angewandte Chemie International Edition, 42(24), 2778-2782. https://doi.org/10.1002/anie.200351096

@article{426e434d60034880ab10aa11d23ace62,

title = "Selective preparation of the [3,5-tBu(2)-1,2,4-C2P3](-) ion and synthesis and structure of the cationic species nido-[3,5-tBu(2)-1,2,4-C2P3](+), isoelectronic with [C5R5](+)",

abstract = "Building pyramids: The first P-C cluster, namely, the novel nido species 2, is readily prepared from 1 (=CtBu), which is also an excellent precursor for the selective synthesis of the anion 3. DFT calculations show that there is a switch in the global minimum, on the introduction of three P atoms (CH) into the [C5H5]+ ion, from cyclic-unsaturated to saturated cage species, such as 2.",

keywords = "anions, cations, density functional calculations, phosphorus, phosphorus heterocycles, STABLE PENTAMETHYLCYCLOPENTADIENYL CATION, ORGANOPHOSPHORUS COMPOUNDS, CRYSTAL-STRUCTURE, VALENCE ISOMER, COMPOUND, C5H5+, BOND",

author = "Lynam, {J M} and Copsey, {M C} and M Green and Jeffery, {J C} and McGrady, {J E} and Russell, {C A} and Slattery, {J M} and Swain, {A C}",

year = "2003",

month = jun,

day = "17",

doi = "10.1002/anie.200351096",

language = "English",

volume = "42",

pages = "2778--2782",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "Wiley-Blackwell",

number = "24",

}

Lynam, JM, Copsey, MC, Green, M, Jeffery, JC, McGrady, JE, Russell, CA, Slattery, JM & Swain, AC 2003, 'Selective preparation of the [3,5-tBu(2)-1,2,4-C2P3](-) ion and synthesis and structure of the cationic species nido-[3,5-tBu(2)-1,2,4-C2P3](+), isoelectronic with [C5R5](+)', Angewandte Chemie International Edition, vol. 42, no. 24, pp. 2778-2782. https://doi.org/10.1002/anie.200351096

Selective preparation of the [3,5-tBu(2)-1,2,4-C2P3](-) ion and synthesis and structure of the cationic species nido-[3,5-tBu(2)-1,2,4-C2P3](+), isoelectronic with [C5R5](+). / Lynam, J M ; Copsey, M C ; Green, M et al.
In: Angewandte Chemie International Edition, Vol. 42, No. 24, 17.06.2003, p. 2778-2782.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Selective preparation of the [3,5-tBu(2)-1,2,4-C2P3](-) ion and synthesis and structure of the cationic species nido-[3,5-tBu(2)-1,2,4-C2P3](+), isoelectronic with [C5R5](+)

AU - Lynam, J M

AU - Copsey, M C

AU - Green, M

AU - Jeffery, J C

AU - McGrady, J E

AU - Russell, C A

AU - Slattery, J M

AU - Swain, A C

PY - 2003/6/17

Y1 - 2003/6/17

N2 - Building pyramids: The first P-C cluster, namely, the novel nido species 2, is readily prepared from 1 (=CtBu), which is also an excellent precursor for the selective synthesis of the anion 3. DFT calculations show that there is a switch in the global minimum, on the introduction of three P atoms (CH) into the [C5H5]+ ion, from cyclic-unsaturated to saturated cage species, such as 2.

AB - Building pyramids: The first P-C cluster, namely, the novel nido species 2, is readily prepared from 1 (=CtBu), which is also an excellent precursor for the selective synthesis of the anion 3. DFT calculations show that there is a switch in the global minimum, on the introduction of three P atoms (CH) into the [C5H5]+ ion, from cyclic-unsaturated to saturated cage species, such as 2.

KW - anions

KW - cations

KW - density functional calculations

KW - phosphorus

KW - phosphorus heterocycles

KW - STABLE PENTAMETHYLCYCLOPENTADIENYL CATION

KW - ORGANOPHOSPHORUS COMPOUNDS

KW - CRYSTAL-STRUCTURE

KW - VALENCE ISOMER

KW - COMPOUND

KW - C5H5+

KW - BOND

U2 - 10.1002/anie.200351096

DO - 10.1002/anie.200351096

M3 - Article

SN - 1433-7851

VL - 42

SP - 2778

EP - 2782

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 24

ER -