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Selective Synthesis of Six Products from a Single Indolyl α-Diazocarbonyl Precursor

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JournalAngewandte Chemie International Edition
DateAccepted/In press - 21 Jun 2016
DateE-pub ahead of print - 20 Jul 2016
DatePublished (current) - 8 Aug 2016
Issue number33
Volume55
Number of pages5
Pages (from-to)9671-9675
Early online date20/07/16
Original languageEnglish

Abstract

Indolyl α-diazocarbonyls can be selectively cyclized to give six distinct products through the careful choice of catalyst and reaction conditions. A range of catalysts were used, including complexes of Rh(II) , Pd(II) , and Cu(II) , as well as SiO2 , to promote diazo decomposition and subsequent cyclization/rearrangement through a range of mechanistic pathways.

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© 2016 Wiley-VCH Verlag GmbH & Co. K. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details. Embargo period : 12 months

    Research areas

  • cyclizations, diazo compounds, indoles, spirocycles, synthetic methods

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