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Selective Synthesis of Six Products from a Single Indolyl α-Diazocarbonyl Precursor
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Publication details
| Journal | Angewandte Chemie International Edition |
|---|---|
| Date | Accepted/In press - 21 Jun 2016 |
| Date | E-pub ahead of print - 20 Jul 2016 |
| Date | Published (current) - 8 Aug 2016 |
| Issue number | 33 |
| Volume | 55 |
| Number of pages | 5 |
| Pages (from-to) | 9671-9675 |
| Early online date | 20/07/16 |
| Original language | English |
Abstract
Indolyl α-diazocarbonyls can be selectively cyclized to give six distinct products through the careful choice of catalyst and reaction conditions. A range of catalysts were used, including complexes of Rh(II) , Pd(II) , and Cu(II) , as well as SiO2 , to promote diazo decomposition and subsequent cyclization/rearrangement through a range of mechanistic pathways.
Bibliographical note
© 2016 Wiley-VCH Verlag GmbH & Co. K. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details. Embargo period : 12 months
- cyclizations, diazo compounds, indoles, spirocycles, synthetic methods
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