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Sequential X-ray-Induced Single-Crystal to Single-Crystal Transformation followed by Topotactic Reduction in a Potassium Crown Ether Complex of Tetrachloroaurate(III)

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JournalInorganic Chemistry
DateAccepted/In press - 21 Sep 2018
DateE-pub ahead of print - 5 Oct 2018
DatePublished (current) - 5 Nov 2018
Issue number21
Number of pages9
Pages (from-to)13524−13532
Early online date5/10/18
Original languageEnglish


During data collection, the unreported potassium crown ether salt [K(18-crown-6][AuCl4] undergoes a sequential X-ray-induced and irreversible single-crystal to single-crystal transformation from P1 to C2/c followed by a topotactic reduction to crystalline [K(18-crown-6][AuCl2] within the same C2/c space group.

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