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[(silox)(2)ReO](2) (silox = (Bu3SiO)-Bu-t) contains a Re equivalent to Re bond and terminal oxo ligands

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Publication details

JournalChemical Communications
DatePublished - 7 Dec 1998
Issue number23
Number of pages2
Pages (from-to)2591-2592
Original languageEnglish

Abstract

The preference for terminal rather than bridging {i.e. [(silox)(2)Re](2)(mu-O)(2)} oxo ligands in C-2 (silox)(2)(O)Re=Re(O)(silox)(2) is electronic, not steric, in origin.

    Research areas

  • COMPLEXES, CHEMISTRY, TUNGSTEN, HYDRIDES

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